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NCERT Solutions

Units and Measurements

Assam Board · Class 11 · Physics

NCERT Solutions for Units and Measurements — Assam Board Class 11 Physics.

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EXERCISES

1.1Fill in the blanks:
(a) The volume of a cube of side 1 cm is equal to ...m³
(b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to ...(mm)²
(c) A vehicle moving with a speed of 18 km h⁻¹ covers...m in 1 s
(d) The relative density of lead is 11.3. Its density is ...g cm⁻³ or ...kg m⁻³.
Show solution
(a) Volume of a cube of side 1 cm in m³:

Given: side =1cm=1×102m= 1\,\text{cm} = 1 \times 10^{-2}\,\text{m}

V=(1×102)3=106m3V = (1\times10^{-2})^3 = 10^{-6}\,\text{m}^3

Answer: 106m310^{-6}\,\text{m}^3

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(b) Surface area of a solid cylinder (radius = 2.0 cm, height = 10.0 cm) in mm²:

Formula: A=2πr(r+h)A = 2\pi r(r + h)

Convert to mm: r=20mmr = 20\,\text{mm}, h=100mmh = 100\,\text{mm}

A=2π×20×(20+100)=2π×20×120A = 2\pi \times 20 \times (20 + 100) = 2\pi \times 20 \times 120
A=2×3.14159×2400=15079.6mm2A = 2 \times 3.14159 \times 2400 = 15079.6\,\text{mm}^2
A1.5×104mm2A \approx 1.5 \times 10^4\,\text{mm}^2

Answer: 1.5×104mm2\approx 1.5 \times 10^4\,\text{mm}^2

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(c) Distance covered in 1 s at 18 km h⁻¹:

18km h1=18×1000m3600s=5m s118\,\text{km h}^{-1} = 18 \times \frac{1000\,\text{m}}{3600\,\text{s}} = 5\,\text{m s}^{-1}

Distance in 1 s =5×1=5m= 5 \times 1 = 5\,\text{m}

Answer: 5m5\,\text{m}

---

(d) Density of lead:

Relative density (specific gravity) =density of substancedensity of water= \dfrac{\text{density of substance}}{\text{density of water}}

Density of water =1g cm3=1000kg m3= 1\,\text{g cm}^{-3} = 1000\,\text{kg m}^{-3}

ρlead=11.3×1g cm3=11.3g cm3\rho_{\text{lead}} = 11.3 \times 1\,\text{g cm}^{-3} = 11.3\,\text{g cm}^{-3}
ρlead=11.3×1000kg m3=1.13×104kg m3\rho_{\text{lead}} = 11.3 \times 1000\,\text{kg m}^{-3} = 1.13 \times 10^4\,\text{kg m}^{-3}

Answer: 11.3g cm311.3\,\text{g cm}^{-3} or 1.13×104kg m31.13 \times 10^4\,\text{kg m}^{-3}
1.2Fill in the blanks by suitable conversion of units:
(a) 1 kg m² s⁻² = ...g cm² s⁻²
(b) 1 m = ... ly
(c) 3.0 m s⁻² = ... km h⁻²
(d) G = 6.67 × 10⁻¹¹ N m² (kg)⁻² = ... (cm)³ s⁻² g⁻¹
Show solution
(a) 1kg m2s21\,\text{kg m}^2\,\text{s}^{-2} in g cm² s⁻²:

1kg=103g1\,\text{kg} = 10^3\,\text{g}, 1m=102cm1\,\text{m} = 10^2\,\text{cm}

1kg m2s2=103g×(102cm)2×s21\,\text{kg m}^2\,\text{s}^{-2} = 10^3\,\text{g} \times (10^2\,\text{cm})^2 \times \text{s}^{-2}
=103×104g cm2s2=107g cm2s2= 10^3 \times 10^4\,\text{g cm}^2\,\text{s}^{-2} = 10^7\,\text{g cm}^2\,\text{s}^{-2}

Answer: 107g cm2s210^7\,\text{g cm}^2\,\text{s}^{-2}

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(b) 1 m in light years (ly):

Speed of light c=3×108m s1c = 3 \times 10^8\,\text{m s}^{-1}

1 year =365.25×24×3600s3.156×107s= 365.25 \times 24 \times 3600\,\text{s} \approx 3.156 \times 10^7\,\text{s}

1ly=3×108×3.156×107=9.467×1015m1\,\text{ly} = 3 \times 10^8 \times 3.156 \times 10^7 = 9.467 \times 10^{15}\,\text{m}

1m=19.467×1015ly1.057×1016ly1\,\text{m} = \frac{1}{9.467 \times 10^{15}}\,\text{ly} \approx 1.057 \times 10^{-16}\,\text{ly}

Answer: 1.057×1016ly\approx 1.057 \times 10^{-16}\,\text{ly}

---

(c) 3.0m s23.0\,\text{m s}^{-2} in km h⁻²:

1m=103km1\,\text{m} = 10^{-3}\,\text{km}, 1s=13600h1\,\text{s} = \dfrac{1}{3600}\,\text{h}, so 1s1=3600h11\,\text{s}^{-1} = 3600\,\text{h}^{-1}

3.0m s2=3.0×103km×(3600)2h23.0\,\text{m s}^{-2} = 3.0 \times 10^{-3}\,\text{km} \times (3600)^2\,\text{h}^{-2}
=3.0×103×1.296×107km h2= 3.0 \times 10^{-3} \times 1.296 \times 10^7\,\text{km h}^{-2}
=3.888×104km h23.9×104km h2= 3.888 \times 10^4\,\text{km h}^{-2} \approx 3.9 \times 10^4\,\text{km h}^{-2}

Answer: 3.9×104km h23.9 \times 10^4\,\text{km h}^{-2}

---

(d) G=6.67×1011N m2kg2G = 6.67 \times 10^{-11}\,\text{N m}^2\,\text{kg}^{-2} in cm³ s⁻² g⁻¹:

Note: 1N=1kg m s21\,\text{N} = 1\,\text{kg m s}^{-2}, so N m2kg2=kg m s2m2kg2=m3s2kg1\text{N m}^2\,\text{kg}^{-2} = \text{kg m s}^{-2} \cdot \text{m}^2 \cdot \text{kg}^{-2} = \text{m}^3\,\text{s}^{-2}\,\text{kg}^{-1}

Convert: 1m3=106cm31\,\text{m}^3 = 10^6\,\text{cm}^3, 1kg1=(103g)1=103g11\,\text{kg}^{-1} = (10^3\,\text{g})^{-1} = 10^{-3}\,\text{g}^{-1}

G=6.67×1011×106cm3×s2×103g1G = 6.67 \times 10^{-11} \times 10^6\,\text{cm}^3 \times \text{s}^{-2} \times 10^{-3}\,\text{g}^{-1}
=6.67×1011×103cm3s2g1= 6.67 \times 10^{-11} \times 10^3\,\text{cm}^3\,\text{s}^{-2}\,\text{g}^{-1}
=6.67×108cm3s2g1= 6.67 \times 10^{-8}\,\text{cm}^3\,\text{s}^{-2}\,\text{g}^{-1}

Answer: 6.67×108cm3s2g16.67 \times 10^{-8}\,\text{cm}^3\,\text{s}^{-2}\,\text{g}^{-1}
1.3A calorie is a unit of heat (energy in transit) and it equals about 4.2 J where 1 J = 1 kg m² s⁻². Suppose we employ a system of units in which the unit of mass equals α kg, the unit of length equals β m, the unit of time is γ s. Show that a calorie has a magnitude 4.2 α⁻¹ β⁻² γ² in terms of the new units.Show solution
Given:
- 1calorie=4.2J=4.2kg m2s21\,\text{calorie} = 4.2\,\text{J} = 4.2\,\text{kg m}^2\,\text{s}^{-2}
- New unit of mass =αkg= \alpha\,\text{kg}, so 1kg=1α1\,\text{kg} = \dfrac{1}{\alpha} (new mass units)
- New unit of length =βm= \beta\,\text{m}, so 1m=1β1\,\text{m} = \dfrac{1}{\beta} (new length units)
- New unit of time =γs= \gamma\,\text{s}, so 1s=1γ1\,\text{s} = \dfrac{1}{\gamma} (new time units)

Dimensional formula of energy: [M1L2T2][M^1 L^2 T^{-2}]

Express 1 calorie in new units:

1calorie=4.2kg m2s21\,\text{calorie} = 4.2\,\text{kg m}^2\,\text{s}^{-2}

Substituting the conversions:

=4.2(1αnew mass unit)(1βnew length unit)2(1γnew time unit)2= 4.2 \left(\frac{1}{\alpha}\,\text{new mass unit}\right) \left(\frac{1}{\beta}\,\text{new length unit}\right)^2 \left(\frac{1}{\gamma}\,\text{new time unit}\right)^{-2}

=4.2×1α×1β2×γ2  (new units of energy)= 4.2 \times \frac{1}{\alpha} \times \frac{1}{\beta^2} \times \gamma^2 \;\text{(new units of energy)}

1calorie=4.2α1β2γ2(in new units)\boxed{1\,\text{calorie} = 4.2\,\alpha^{-1}\beta^{-2}\gamma^{2}\,\text{(in new units)}}

This is the required result. \blacksquare
1.4Explain this statement clearly: 'To call a dimensional quantity large or small is meaningless without specifying a standard for comparison'. In view of this, reframe the following statements wherever necessary:
(a) atoms are very small objects
(b) a jet plane moves with great speed
(c) the mass of Jupiter is very large
(d) the air inside this room contains a large number of molecules
(e) a proton is much more massive than an electron
(f) the speed of sound is much smaller than the speed of light.
Show solution
Explanation of the statement:

A physical quantity has magnitude only in relation to a chosen standard (unit). Saying something is 'large' or 'small' is meaningful only when we compare it with a reference standard. For example, the size of an atom (~101010^{-10} m) is small compared to everyday objects but large compared to a nucleus (~101510^{-15} m). Without specifying the comparison standard, such statements are incomplete and meaningless.

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(a) Atoms are very small objects.

This statement is incomplete as stated. Reframed:

*Atoms are very small objects compared to the ordinary objects around us (e.g., a grain of sand or a human hair).*

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(b) A jet plane moves with great speed.

This statement is incomplete. Reframed:

*A jet plane moves with a speed much greater than that of a car or a train (but much smaller than the speed of light).*

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(c) The mass of Jupiter is very large.

This statement is incomplete. Reframed:

*The mass of Jupiter is very large compared to the mass of the Earth (Jupiter's mass 318\approx 318 times the Earth's mass).*

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(d) The air inside this room contains a large number of molecules.

This statement is incomplete. Reframed:

*The air inside this room contains a very large number of molecules compared to, say, the number of people in the room (or compared to Avogadro's number as a reference).*

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(e) A proton is much more massive than an electron.

This statement is already meaningful because it specifies a comparison standard (the electron). No reframing needed.

*A proton is about 1836 times more massive than an electron.*

---

(f) The speed of sound is much smaller than the speed of light.

This statement is already meaningful because it specifies a comparison standard (the speed of light). No reframing needed.

*Speed of sound 340m s1\approx 340\,\text{m s}^{-1}, speed of light =3×108m s1= 3 \times 10^8\,\text{m s}^{-1}; the speed of sound is much smaller than the speed of light.*
1.5A new unit of length is chosen such that the speed of light in vacuum is unity. What is the distance between the Sun and the Earth in terms of the new unit if light takes 8 min and 20 s to cover this distance?Show solution
Given:
- Speed of light in new units: c=1c = 1 (new unit of length per new unit of time)
- Time taken by light to travel from Sun to Earth: t=8min20st = 8\,\text{min}\,20\,\text{s}

Convert time to seconds:
t=8×60+20=480+20=500st = 8 \times 60 + 20 = 480 + 20 = 500\,\text{s}

Using: Distance == Speed ×\times Time

d=c×t=1×500=500new units of lengthd = c \times t = 1 \times 500 = 500\,\text{new units of length}

Answer: The distance between the Sun and the Earth is 500 new units of length.

(This new unit is essentially 1 light-second, and the Sun–Earth distance is 500 light-seconds.)
1.6Which of the following is the most precise device for measuring length:
(a) a vernier callipers with 20 divisions on the sliding scale
(b) a screw gauge of pitch 1 mm and 100 divisions on the circular scale
(c) an optical instrument that can measure length to within a wavelength of light?
Show solution
Concept: Precision of a measuring instrument is determined by its least count (smallest measurement it can make).

(a) Vernier callipers with 20 divisions on sliding scale:

Least count =1MSDnumber of VSD=1mm20=0.05mm=5×105m= \dfrac{1\,\text{MSD}}{\text{number of VSD}} = \dfrac{1\,\text{mm}}{20} = 0.05\,\text{mm} = 5 \times 10^{-5}\,\text{m}

(b) Screw gauge with pitch 1 mm and 100 divisions:

Least count =pitchnumber of divisions=1mm100=0.01mm=105m= \dfrac{\text{pitch}}{\text{number of divisions}} = \dfrac{1\,\text{mm}}{100} = 0.01\,\text{mm} = 10^{-5}\,\text{m}

(c) Optical instrument measuring to within a wavelength of light:

Wavelength of visible light 4000A˚\approx 4000\,\text{Å} to 7000A˚7000\,\text{Å}, i.e., 107m\approx 10^{-7}\,\text{m}

Least count 107m\approx 10^{-7}\,\text{m}

Comparison:
- (a): 5×105m5 \times 10^{-5}\,\text{m}
- (b): 105m10^{-5}\,\text{m}
- (c): 107m\sim 10^{-7}\,\text{m}smallest least count

Answer: The optical instrument (c) is the most precise device, as it has the smallest least count (~10710^{-7} m).
1.7A student measures the thickness of a human hair by looking at it through a microscope of magnification 100. He makes 20 observations and finds that the average width of the hair in the field of view of the microscope is 3.5 mm. What is the estimate on the thickness of hair?Show solution
Given:
- Magnification of microscope =100= 100
- Average observed width of hair (magnified image) =3.5mm= 3.5\,\text{mm}

Formula:
Actual thickness=Observed widthMagnification\text{Actual thickness} = \frac{\text{Observed width}}{\text{Magnification}}

Actual thickness=3.5mm100=0.035mm\text{Actual thickness} = \frac{3.5\,\text{mm}}{100} = 0.035\,\text{mm}

Answer: The estimated thickness of human hair is 0.035mm\mathbf{0.035\,\text{mm}} (i.e., 3.5×102mm3.5 \times 10^{-2}\,\text{mm}).
1.8Answer the following:
(a) You are given a thread and a metre scale. How will you estimate the diameter of the thread?
(b) A screw gauge has a pitch of 1.0 mm and 200 divisions on the circular scale. Do you think it is possible to increase the accuracy of the screw gauge arbitrarily by increasing the number of divisions on the circular scale?
(c) The mean diameter of a thin brass rod is to be measured by vernier callipers. Why is a set of 100 measurements of the diameter expected to yield a more reliable estimate than a set of 5 measurements only?
Show solution
(a) Estimating the diameter of a thread using a thread and metre scale:

Wind the thread closely and uniformly on a pencil or a cylindrical rod for a known number of turns nn (say 20 or more turns), such that the turns are touching each other without gaps or overlaps. Measure the total length LL of the winding using the metre scale.

Diameter of thread=Ln\text{Diameter of thread} = \frac{L}{n}

This method averages out the error over many turns, giving a more accurate estimate.

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(b) Can accuracy of screw gauge be increased arbitrarily by increasing divisions on circular scale?

The least count of a screw gauge is:
Least count=PitchNumber of divisions on circular scale\text{Least count} = \frac{\text{Pitch}}{\text{Number of divisions on circular scale}}

For pitch =1.0mm= 1.0\,\text{mm} and 200 divisions:
LC=1.0200=0.005mm\text{LC} = \frac{1.0}{200} = 0.005\,\text{mm}

No, it is not possible to increase accuracy arbitrarily by simply increasing the number of divisions. Beyond a certain limit:
- The divisions become too small to be read accurately by the human eye.
- Manufacturing imperfections and mechanical backlash introduce errors that cannot be eliminated by finer graduation.
- The instrument's mechanical precision sets a fundamental limit.

Thus, increasing divisions beyond a practical limit does not improve accuracy.

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(c) Why does a set of 100 measurements give a more reliable estimate than 5 measurements?

In any measurement, there are random errors that can be positive or negative. When a large number of measurements are taken:
- Random errors tend to cancel out (some are positive, some negative).
- The mean of a large number of observations is closer to the true value.
- The standard error of the mean =σn= \dfrac{\sigma}{\sqrt{n}}, where σ\sigma is the standard deviation and nn is the number of measurements.

For n=100n = 100: standard error =σ10= \dfrac{\sigma}{10}

For n=5n = 5: standard error =σ5σ2.24= \dfrac{\sigma}{\sqrt{5}} \approx \dfrac{\sigma}{2.24}

Since σ10σ2.24\dfrac{\sigma}{10} \ll \dfrac{\sigma}{2.24}, 100 measurements give a far more reliable (precise) estimate of the true diameter.
1.9The photograph of a house occupies an area of 1.75 cm² on a 35 mm slide. The slide is projected on to a screen, and the area of the house on the screen is 1.55 m². What is the linear magnification of the projector-screen arrangement?Show solution
Given:
- Area of house on slide: A1=1.75cm2=1.75×104m2A_1 = 1.75\,\text{cm}^2 = 1.75 \times 10^{-4}\,\text{m}^2
- Area of house on screen: A2=1.55m2A_2 = 1.55\,\text{m}^2

Concept: If linear magnification is mm, then areal magnification =m2= m^2.

m2=A2A1=1.551.75×104=1.550.000175=8857m^2 = \frac{A_2}{A_1} = \frac{1.55}{1.75 \times 10^{-4}} = \frac{1.55}{0.000175} = 8857

m=885794.1m = \sqrt{8857} \approx 94.1

Answer: The linear magnification of the projector-screen arrangement is approximately 94.1\mathbf{94.1}.
1.10State the number of significant figures in the following:
(a) 0.007 m²
(b) 2.64 × 10²⁴ kg
(c) 0.2370 g cm⁻³
(d) 6.320 J
(e) 6.032 N m⁻²
(f) 0.0006032 m²
Show solution
Rules for significant figures:
- All non-zero digits are significant.
- Zeros between non-zero digits are significant.
- Leading zeros (before the first non-zero digit) are NOT significant.
- Trailing zeros after the decimal point ARE significant.
- In scientific notation, all digits in the coefficient are significant.

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(a) 0.007m20.007\,\text{m}^2:

Leading zeros are not significant. Only the digit 7 is significant.

Number of significant figures = 1

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(b) 2.64×1024kg2.64 \times 10^{24}\,\text{kg}:

Digits 2, 6, 4 are all significant.

Number of significant figures = 3

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(c) 0.2370g cm30.2370\,\text{g cm}^{-3}:

Leading zero is not significant. Digits 2, 3, 7, 0 are significant (trailing zero after decimal is significant).

Number of significant figures = 4

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(d) 6.320J6.320\,\text{J}:

Digits 6, 3, 2, 0 are all significant (trailing zero after decimal is significant).

Number of significant figures = 4

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(e) 6.032N m26.032\,\text{N m}^{-2}:

Digits 6, 0, 3, 2 are all significant (zero between non-zero digits is significant).

Number of significant figures = 4

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(f) 0.0006032m20.0006032\,\text{m}^2:

Leading zeros are not significant. Digits 6, 0, 3, 2 are significant.

Number of significant figures = 4
1.11The length, breadth and thickness of a rectangular sheet of metal are 4.234 m, 1.005 m, and 2.01 cm respectively. Give the area and volume of the sheet to correct significant figures.Show solution
Given:
- Length l=4.234ml = 4.234\,\text{m} (4 significant figures)
- Breadth b=1.005mb = 1.005\,\text{m} (4 significant figures)
- Thickness t=2.01cm=0.0201mt = 2.01\,\text{cm} = 0.0201\,\text{m} (3 significant figures)

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Area of the sheet:

Area =l×b= l \times b (the two largest faces)

A=4.234×1.005=4.255170m2A = 4.234 \times 1.005 = 4.255170\,\text{m}^2

For multiplication, the result should have the same number of significant figures as the quantity with the fewest significant figures. Both ll and bb have 4 significant figures.

A4.255m2\boxed{A \approx 4.255\,\text{m}^2}

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Volume of the sheet:

V=l×b×t=4.234×1.005×0.0201V = l \times b \times t = 4.234 \times 1.005 \times 0.0201

=4.255170×0.0201=0.08552892m3= 4.255170 \times 0.0201 = 0.08552892\,\text{m}^3

The least number of significant figures among ll, bb, tt is 3 (thickness has 3 sig. figs.).

V0.0855m3\boxed{V \approx 0.0855\,\text{m}^3}

(i.e., 8.55×102m38.55 \times 10^{-2}\,\text{m}^3, rounded to 3 significant figures)
1.12The mass of a box measured by a grocer's balance is 2.30 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is (a) the total mass of the box, (b) the difference in the masses of the pieces to correct significant figures?Show solution
Given:
- Mass of box M=2.30kg=2300gM = 2.30\,\text{kg} = 2300\,\text{g}
- Mass of gold piece 1: m1=20.15gm_1 = 20.15\,\text{g}
- Mass of gold piece 2: m2=20.17gm_2 = 20.17\,\text{g}

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(a) Total mass of the box:

Mtotal=2300g+20.15g+20.17g=2340.32gM_{\text{total}} = 2300\,\text{g} + 20.15\,\text{g} + 20.17\,\text{g} = 2340.32\,\text{g}

Rule for addition: The result should be rounded to the same decimal place as the number with the least decimal places.

- 2300g2300\,\text{g} has no decimal places (it is certain only to the nearest 10 g, since 2.30 kg means the last certain digit is in the hundredths of kg = tens of grams).

Actually, 2.30kg2.30\,\text{kg} is precise to 0.01kg=10g0.01\,\text{kg} = 10\,\text{g}.

So the total should be rounded to the nearest 10 g:

Mtotal2340g=2.34kgM_{\text{total}} \approx 2340\,\text{g} = 2.34\,\text{kg}

Answer: Total mass =2.34kg= \mathbf{2.34\,\text{kg}}

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(b) Difference in masses of the two gold pieces:

Δm=m2m1=20.1720.15=0.02g\Delta m = m_2 - m_1 = 20.17 - 20.15 = 0.02\,\text{g}

Both masses are given to 2 decimal places (hundredths of a gram), so the result is also expressed to 2 decimal places.

Answer: Difference in masses =0.02g= \mathbf{0.02\,\text{g}} (1 significant figure)
1.13A famous relation in physics relates 'moving mass' m to the 'rest mass' m₀ of a particle in terms of its speed v and the speed of light, c. A boy recalls the relation almost correctly but forgets where to put the constant c. He writes:
m=m0(1v2)1/2m = \frac{m_0}{(1-v^2)^{1/2}}
Guess where to put the missing c.
Show solution
Given (incorrect) relation:
m=m0(1v2)1/2m = \frac{m_0}{(1 - v^2)^{1/2}}

Dimensional Analysis:

The left-hand side has dimensions of mass: [M][M].

The right-hand side: m0m_0 has dimensions [M][M]. For the equation to be dimensionally consistent, the denominator must be dimensionless.

The term (1v2)1/2(1 - v^2)^{1/2} is dimensionless only if v2v^2 is dimensionless. But vv has dimensions [LT1][LT^{-1}], so v2v^2 has dimensions [L2T2][L^2T^{-2}], which is NOT dimensionless.

Correction:

To make v2v^2 dimensionless, we must divide it by c2c^2 (which also has dimensions [L2T2][L^2T^{-2}]):

v2c2 is dimensionless\frac{v^2}{c^2} \text{ is dimensionless}

Therefore, the correct relation is:

m=m0(1v2c2)1/2\boxed{m = \frac{m_0}{\left(1 - \dfrac{v^2}{c^2}\right)^{1/2}}}

This is indeed the correct relativistic mass formula from Einstein's special theory of relativity.
1.14The unit of length convenient on the atomic scale is known as an angstrom and is denoted by Å: 1 Å = 10⁻¹⁰ m. The size of a hydrogen atom is about 0.5 Å. What is the total atomic volume in m³ of a mole of hydrogen atoms?Show solution
Given:
- Radius of hydrogen atom r=0.5A˚=0.5×1010m=5×1011mr = 0.5\,\text{Å} = 0.5 \times 10^{-10}\,\text{m} = 5 \times 10^{-11}\,\text{m}
- Number of atoms in 1 mole =NA=6.023×1023= N_A = 6.023 \times 10^{23}

Volume of one hydrogen atom (treated as a sphere):

Vatom=43πr3=43×3.14159×(5×1011)3V_{\text{atom}} = \frac{4}{3}\pi r^3 = \frac{4}{3} \times 3.14159 \times (5 \times 10^{-11})^3

=43×3.14159×125×1033= \frac{4}{3} \times 3.14159 \times 125 \times 10^{-33}

=43×3.14159×1.25×1031= \frac{4}{3} \times 3.14159 \times 1.25 \times 10^{-31}

=5.236×1031m3= 5.236 \times 10^{-31}\,\text{m}^3

Total atomic volume of 1 mole of hydrogen atoms:

Vtotal=NA×Vatom=6.023×1023×5.236×1031V_{\text{total}} = N_A \times V_{\text{atom}} = 6.023 \times 10^{23} \times 5.236 \times 10^{-31}

=6.023×5.236×108= 6.023 \times 5.236 \times 10^{-8}

=31.54×1083.154×107m3= 31.54 \times 10^{-8} \approx 3.154 \times 10^{-7}\,\text{m}^3

Answer: Total atomic volume 3.154×107m3\approx \mathbf{3.154 \times 10^{-7}\,\text{m}^3}
1.15One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1 Å). Why is this ratio so large?Show solution
Given:
- Molar volume of ideal gas Vmolar=22.4L=22.4×103m3V_{\text{molar}} = 22.4\,\text{L} = 22.4 \times 10^{-3}\,\text{m}^3
- Size of hydrogen molecule 1A˚\approx 1\,\text{Å}, so radius r=0.5A˚=0.5×1010mr = 0.5\,\text{Å} = 0.5 \times 10^{-10}\,\text{m}
- NA=6.023×1023N_A = 6.023 \times 10^{23}

Atomic volume of 1 mole of hydrogen molecules:

Vatom=43πr3=43×3.14159×(0.5×1010)3V_{\text{atom}} = \frac{4}{3}\pi r^3 = \frac{4}{3} \times 3.14159 \times (0.5 \times 10^{-10})^3

=43×3.14159×1.25×1031=5.236×1031m3= \frac{4}{3} \times 3.14159 \times 1.25 \times 10^{-31} = 5.236 \times 10^{-31}\,\text{m}^3

Vtotal atomic=NA×Vatom=6.023×1023×5.236×1031V_{\text{total atomic}} = N_A \times V_{\text{atom}} = 6.023 \times 10^{23} \times 5.236 \times 10^{-31}
=3.154×107m3= 3.154 \times 10^{-7}\,\text{m}^3

Ratio:

VmolarVtotal atomic=22.4×1033.154×107=2.24×1023.154×1077.1×104\frac{V_{\text{molar}}}{V_{\text{total atomic}}} = \frac{22.4 \times 10^{-3}}{3.154 \times 10^{-7}} = \frac{2.24 \times 10^{-2}}{3.154 \times 10^{-7}} \approx 7.1 \times 10^4

Answer: The ratio is approximately 7.1×104\mathbf{7.1 \times 10^4}.

Why is this ratio so large?

This ratio is large because in a gas at standard temperature and pressure, the molecules are far apart from each other. The actual volume occupied by the molecules themselves is negligibly small compared to the total volume of the gas. Most of the volume of a gas is empty space. This is a fundamental difference between gases and solids/liquids, where molecules are closely packed.
1.16Explain this common observation clearly: If you look out of the window of a fast moving train, the nearby trees, houses etc. seem to move rapidly in a direction opposite to the train's motion, but the distant objects (hill tops, the Moon, the stars etc.) seem to be stationary. (In fact, since you are aware that you are moving, these distant objects seem to move with you).Show solution
Explanation using the concept of parallax:

This observation is explained by the principle of parallax. The apparent shift in the position of an object due to a change in the position of the observer is called parallax.

When you are in a moving train, your position changes continuously. The angular velocity (rate of change of angle subtended at the observer's eye) of an object depends on its distance from the observer.

For a nearby object at distance dd, if the train moves a distance Δx\Delta x in time Δt\Delta t, the angle subtended changes by:
ΔθΔxd\Delta\theta \approx \frac{\Delta x}{d}

The angular velocity =ΔθΔt=vd= \dfrac{\Delta\theta}{\Delta t} = \dfrac{v}{d}, where vv is the speed of the train.

- Nearby objects (small dd): vd\dfrac{v}{d} is large → they appear to move rapidly in the opposite direction.

- Distant objects (very large dd, like hills, Moon, stars): vd0\dfrac{v}{d} \approx 0 → they appear stationary or seem to move along with you.

Thus, the apparent motion of objects is inversely proportional to their distance from the observer. Nearby objects show large parallax (appear to move fast in opposite direction), while very distant objects show negligible parallax (appear stationary or to move with the observer).
1.17The Sun is a hot plasma (ionized matter) with its inner core at a temperature exceeding 10⁷ K, and its outer surface at a temperature of about 6000 K. At these high temperatures, no substance remains in a solid or liquid phase. In what range do you expect the mass density of the Sun to be, in the range of densities of solids and liquids or gases? Check if your guess is correct from the following data: mass of the Sun = 2.0 × 10³⁰ kg, radius of the Sun = 7.0 × 10⁸ m.Show solution
Initial Guess:

Since the Sun is made of plasma at very high temperatures, one might initially guess that its density would be in the range of gases (which are much less dense than solids/liquids). However, the Sun has an enormous gravitational force that compresses the matter, so the density could be much higher.

Calculation of the Sun's average density:

Given:
- Mass of Sun M=2.0×1030kgM = 2.0 \times 10^{30}\,\text{kg}
- Radius of Sun R=7.0×108mR = 7.0 \times 10^8\,\text{m}

Volume of Sun (assuming spherical):
V=43πR3=43×3.14159×(7.0×108)3V = \frac{4}{3}\pi R^3 = \frac{4}{3} \times 3.14159 \times (7.0 \times 10^8)^3

=43×3.14159×343×1024= \frac{4}{3} \times 3.14159 \times 343 \times 10^{24}

=43×3.14159×3.43×1026= \frac{4}{3} \times 3.14159 \times 3.43 \times 10^{26}

=4.189×3.43×1026=1.437×1027m3= 4.189 \times 3.43 \times 10^{26} = 1.437 \times 10^{27}\,\text{m}^3

Average density:
ρ=MV=2.0×10301.437×1027=2.01.437×1031.39×103kg m3\rho = \frac{M}{V} = \frac{2.0 \times 10^{30}}{1.437 \times 10^{27}} = \frac{2.0}{1.437} \times 10^3 \approx 1.39 \times 10^3\,\text{kg m}^{-3}

ρ1.4×103kg m3=1.4g cm3\rho \approx 1.4 \times 10^3\,\text{kg m}^{-3} = 1.4\,\text{g cm}^{-3}

Comparison:
- Density of gases: 1kg m3\sim 1\,\text{kg m}^{-3} (e.g., air 1.3kg m3\approx 1.3\,\text{kg m}^{-3})
- Density of water: 1000kg m31000\,\text{kg m}^{-3}
- Density of solids/liquids: 10310^3 to 104kg m310^4\,\text{kg m}^{-3}

Conclusion:

The average density of the Sun (1.4×103kg m3\approx 1.4 \times 10^3\,\text{kg m}^{-3}) is in the range of solids and liquids, not gases. Despite being a plasma at very high temperatures, the Sun's enormous gravitational self-compression keeps its average density comparable to that of water. This confirms that the gravitational compression dominates over the thermal expansion tendency.

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