Chemical Kinetics
Bihar Board · Class 12 · Chemistry
Most important questions from Chemical Kinetics for Bihar Board Class 12 Chemistry board exam 2026. MCQs, short answer, and long answer questions with marks.
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Which of the following factors affect the rate of a chemical reaction?
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Temperature, Concentration of reactants, Presence of catalyst, Pressure (for gaseous reactions)
Temperature increases molecular kinetic energy, concentration affects collision frequency, catalysts provide alternate pathways with lower activation energy, and pressure affects concentration of gases. Molecular weight of products does not directly affect reaction rate.
Which of the following statements about molecularity are correct?
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It is always a whole number, It is defined only for elementary reactions, It represents the number of molecules participating in an elementary reaction
Molecularity is always a positive integer (1, 2, or 3) representing the number of molecules that must collide simultaneously in an elementary reaction. It cannot be zero or fractional, unlike order of reaction.
For a first-order reaction, if the initial concentration is doubled, the half-life will:
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Remain the same
For first-order reactions, t₁/₂ = 0.693/k, which is independent of initial concentration. This is a characteristic property of first-order reactions - their half-life remains constant.
According to collision theory, which factors determine effective collisions?
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Sufficient kinetic energy (threshold energy), Proper orientation of molecules
Effective collisions require two main conditions: molecules must have kinetic energy equal to or greater than the threshold energy, and they must collide with proper orientation to facilitate bond breaking and formation.
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