p-Block Group 14 Elements: The Carbon Family — Syllabus
JEE Mains · Chemistry
Free p-Block Group 14 Elements: The Carbon Family syllabus for JEE Mains Chemistry 2026 — topics covered, weightage, and preparation priorities for this chapter.
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Topics covered in p-Block Group 14 Elements: The Carbon Family for JEE Mains Chemistry.
Topics in p-Block Group 14 Elements: The Carbon Family
General Characteristics and Periodic Trends
- Electronic configuration: ns²np² where n = 2 to 6
- Metallic character: C (non-metal) → Si (metalloid) → Ge (metalloid) → Sn, Pb (metals)
- Covalent radii order: C < Si < Ge < Sn < Pb
Allotropes of Carbon
- Diamond: sp³ hybridized, tetrahedral structure, hardest substance, electrical insulator
- Graphite: sp² hybridized, layered structure with π-electrons, conducts electricity
- Fullerenes: C₆₀ (12 pentagons + 20 hexagons), C₇₀ (12 pentagons + 25 hexagons)
Oxides of Group 14 Elements
- Monoxides (MO): CO (neutral), SiO (high temp only), GeO, SnO, PbO (amphoteric)
- Dioxides (MO₂): CO₂ (acidic), SiO₂ (weakly acidic), GeO₂, SnO₂ (amphoteric), PbO₂ (basic)
- Acidic character decreases: CO₂ > SiO₂ > GeO₂ > SnO₂ > PbO₂
Hydrides and Halides
- Hydrides: CH₄ (most stable) > SiH₄ > GeH₄ > SnH₄ > PbH₄ (thermal stability decreases)
- Reducing character of hydrides increases down the group
- Tetrahalides (MX₄): All elements form except PbBr₄ and PbI₄ (don't exist)
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