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Syllabus

p-Block Group 14 Elements: The Carbon FamilySyllabus

JEE Mains · Chemistry

Free p-Block Group 14 Elements: The Carbon Family syllabus for JEE Mains Chemistry 2026 — topics covered, weightage, and preparation priorities for this chapter.

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A comparison chart highlighting the key similarities and dissimilarities between Silicon (Si) and Tin (Sn) in terms of allotropy, oxides, hydrides, halides, reaction with alkalis, metallic character,
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p-Block Group 14 Elements: The Carbon Family — Syllabus & Topics

Topics covered in p-Block Group 14 Elements: The Carbon Family for JEE Mains Chemistry.

Topics in p-Block Group 14 Elements: The Carbon Family

1

General Characteristics and Periodic Trends

  • Electronic configuration: ns²np² where n = 2 to 6
  • Metallic character: C (non-metal) → Si (metalloid) → Ge (metalloid) → Sn, Pb (metals)
  • Covalent radii order: C < Si < Ge < Sn < Pb
2

Allotropes of Carbon

  • Diamond: sp³ hybridized, tetrahedral structure, hardest substance, electrical insulator
  • Graphite: sp² hybridized, layered structure with π-electrons, conducts electricity
  • Fullerenes: C₆₀ (12 pentagons + 20 hexagons), C₇₀ (12 pentagons + 25 hexagons)
3

Oxides of Group 14 Elements

  • Monoxides (MO): CO (neutral), SiO (high temp only), GeO, SnO, PbO (amphoteric)
  • Dioxides (MO₂): CO₂ (acidic), SiO₂ (weakly acidic), GeO₂, SnO₂ (amphoteric), PbO₂ (basic)
  • Acidic character decreases: CO₂ > SiO₂ > GeO₂ > SnO₂ > PbO₂
4

Hydrides and Halides

  • Hydrides: CH₄ (most stable) > SiH₄ > GeH₄ > SnH₄ > PbH₄ (thermal stability decreases)
  • Reducing character of hydrides increases down the group
  • Tetrahalides (MX₄): All elements form except PbBr₄ and PbI₄ (don't exist)

Key Concepts

All Group 14 elements have ns²np²Group oxidation state is +4Carbon shows exceptional catenation dueDiamondCO

Frequently Asked Questions

What topics are covered in p-Block Group 14 Elements: The Carbon Family for JEE Mains?
p-Block Group 14 Elements: The Carbon Family is an important chapter in JEE Mains Chemistry. It covers key concepts and formulas that are frequently tested in the exam. Key topics include: General Characteristics and Periodic Trends, Allotropes of Carbon, Oxides of Group 14 Elements, Hydrides and Halides.
How important is p-Block Group 14 Elements: The Carbon Family for JEE Mains?
p-Block Group 14 Elements: The Carbon Family is a frequently tested chapter in JEE Mains Chemistry. Questions from this chapter appear regularly in previous year papers. There are 57 practice questions available for this chapter.
How to prepare p-Block Group 14 Elements: The Carbon Family for JEE Mains?
Start by understanding the core concepts, then solve practice questions. Focus on formulas and their applications. Use revision notes for quick review before the exam.

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