Electrochemistry
Tripura Board · Class 12 · Chemistry
Most important questions from Electrochemistry for Tripura Board Class 12 Chemistry board exam 2026. MCQs, short answer, and long answer questions with marks.
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Which of the following are characteristics of electrolytic conductivity? (Select all correct answers)
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It increases with increase in temperature, It depends on the nature of the electrolyte, It is due to movement of ions
Electrolytic conductivity increases with temperature as ions move faster, depends on the electrolyte type, and is caused by ion movement. Conductivity actually increases with concentration (up to a point) and is affected by solvent viscosity.
Which of the following factors affect the conductivity of an electrolytic solution? (Select all correct answers)
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Nature of the electrolyte, Size of ions and their solvation, Concentration of the electrolyte, Nature of the solvent
Conductivity depends on the type of electrolyte, ion size and solvation (which affects mobility), concentration of ions, and solvent properties like viscosity. The color of the solution does not affect conductivity.
The unit of molar conductivity is:
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S cm² mol⁻¹
Molar conductivity (Λm) has units of S cm² mol⁻¹ (siemens square centimeter per mole). It is calculated as κ/c, where κ has units S cm⁻¹ and c has units mol cm⁻³, giving the result in S cm² mol⁻¹.
According to Kohlrausch's law, the molar conductivity at infinite dilution is:
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Sum of individual ionic conductivities
Kohlrausch's law states that the limiting molar conductivity (at infinite dilution) of an electrolyte is the sum of the limiting molar conductivities of its constituent ions: Λ°m = λ°+ + λ°-
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