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Chemistry Formulas for Class 12 — Complete Formula Sheet 2026

All Chemistry formulas for Class 12 CBSE and competitive exams — Physical, Organic, Inorganic organised chapter-wise for quick reference.

This is your complete Class 12 Chemistry formula sheet — organised by chapter. Bookmark this page and review it daily. Physical Chemistry formulas are the most numerical-heavy; Organic has more reactions than formulas; Inorganic is mostly factual.

Physical Chemistry Formulas

Solutions (Chapter 1)

FormulaDescription
Molarity (M) = moles of solute / volume of solution (L)Concentration in mol/L
Molality (m) = moles of solute / mass of solvent (kg)Concentration independent of temperature
Raoult's Law: P = P°A × xA + P°B × xBVapour pressure of ideal solution
ΔTb = Kb × m × iBoiling point elevation
ΔTf = Kf × m × iFreezing point depression
π = iCRTOsmotic pressure
i = 1 + (n−1)αvan't Hoff factor (dissociation)
i = 1 − α + α/nvan't Hoff factor (association)

Electrochemistry (Chapter 2)

FormulaDescription
E°cell = E°cathode − E°anodeStandard cell potential
ΔG° = −nFE°cellGibbs energy from cell potential
Nernst: E = E° − (RT/nF) ln QCell potential at non-standard conditions
Nernst (at 25°C): E = E° − (0.0591/n) log QSimplified Nernst equation
Λm = κ × 1000 / MMolar conductivity
Kohlrausch: Λ°m = λ°+ + λ°−Limiting molar conductivity
Faraday: m = (M × I × t) / (n × F)Mass deposited in electrolysis

Chemical Kinetics (Chapter 3)

FormulaDescription
Rate = k[A]ⁿ[B]ᵐRate law expression
Zero order: [A] = [A]₀ − ktConcentration vs time
First order: k = (2.303/t) log([A]₀/[A])First order rate constant
t½ = 0.693/k (first order)Half-life (independent of concentration)
t½ = [A]₀/2k (zero order)Half-life (depends on initial concentration)
Arrhenius: k = Ae^(−Ea/RT)Rate constant vs temperature
log(k₂/k₁) = (Ea/2.303R)(1/T₁ − 1/T₂)Two-temperature Arrhenius form

Thermodynamics & Equilibrium

FormulaDescription
ΔG = ΔH − TΔSGibbs free energy
ΔG° = −RT ln KGibbs energy and equilibrium constant
ΔG° = −2.303RT log KLog form
Kp = Kc(RT)^ΔnRelation between Kp and Kc
pH = −log[H⁺]pH definition
pOH = −log[OH⁻]pOH definition
pH + pOH = 14 (at 25°C)Water equilibrium
pH = pKa + log([A⁻]/[HA])Henderson-Hasselbalch equation

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Organic Chemistry — Key Reactions & Rules

Named Reactions (Board Favourites)

ReactionWhat It Does
Sandmeyer ReactionArN₂⁺ + CuX → ArX (Cl, Br, CN)
Kolbe's ReactionPhenol + NaOH + CO₂ → Salicylic acid
Reimer-Tiemann ReactionPhenol + CHCl₃ + NaOH → Salicylaldehyde
Williamson SynthesisR-ONa + R'-X → R-O-R' (ether)
Aldol CondensationAldehyde with α-H + dil. NaOH → β-hydroxy aldehyde
Cannizzaro ReactionAldehyde without α-H + conc. NaOH → acid + alcohol
Hell-Volhard-ZelinskyCarboxylic acid + Br₂/P → α-bromo acid
Hofmann BromamideRCONH₂ + Br₂ + NaOH → RNH₂ (−1 carbon)
Gabriel PhthalimidePhthalimide + R-X + KOH → primary amine
Coupling ReactionArN₂⁺Cl⁻ + ArOH/ArNH₂ → Azo dye

Reagent-Based Conversions

ConversionReagent
Alcohol → AldehydePCC or Collins reagent (mild oxidation)
Alcohol → Carboxylic acidKMnO₄ or K₂Cr₂O₇ (strong oxidation)
Aldehyde → AlcoholNaBH₄ or LiAlH₄ (reduction)
Carboxylic acid → AlcoholLiAlH₄ (strong reduction)
Alkyl halide → AlcoholAq. NaOH (SN2 for 1°)
Amine → Diazonium saltNaNO₂ + HCl at 0–5°C

Inorganic Chemistry — Key Facts

TopicKey Formula/Fact
Crystal Field SplittingΔo (octahedral) > Δt (tetrahedral); Δt ≈ 4/9 Δo
Magnetic Momentμ = √(n(n+2)) BM, where n = unpaired electrons
Coordination NumberCN 4: tetrahedral/square planar; CN 6: octahedral
EAN RuleEAN = Z − oxidation state + 2 × coordination number
Lattice EnergyBorn-Landé equation; ∝ charge, ∝ 1/distance

How to Use This Formula Sheet

  1. Print or bookmark. Review for 15 minutes every morning.
  2. After each formula, solve 2–3 numericals. Reading ≠ learning. Solving = learning.
  3. Make your own handwritten sheet. Writing activates motor memory — much stronger than reading.
  4. Before the exam: write the top 20 formulas from memory on rough paper. This "brain dump" prevents blanking out.

Formulas based on NCERT Class 12 Chemistry (2025–2026 syllabus). Some symbols simplified for readability. For complete derivations, refer to NCERT textbooks. Useful for CBSE boards, JEE Main, and NEET. Last updated: February 2026.

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Frequently Asked Questions

How many formulas are there in Class 12 Chemistry?

Approximately 80–100 key formulas across Physical, Organic, and Inorganic Chemistry. Physical Chemistry has the most formulas (50+). Organic Chemistry has fewer formulas but more named reactions (20+). Inorganic Chemistry is more fact-based than formula-based. Focus on the 40–50 most frequently tested formulas first.

Top priority: Nernst equation, Kohlrausch law, rate law expressions, Arrhenius equation, Raoult's law, van't Hoff factor, pH/pOH formulas, crystal field splitting energy. These appear in numericals worth 3–5 marks. For Organic: IUPAC naming rules and reagent-based reactions are more important than formulas.

Write each formula 5 times by hand. Understand what each symbol represents (do not just memorise the letters). Solve 3–5 numericals per formula immediately. Use spaced repetition: revise Day 1, Day 3, Day 7, Day 14. Group related formulas together (e.g., all colligative property formulas). Make a 2-page formula sheet and review it daily.

These cover the NCERT syllabus which is the foundation for both JEE and NEET. JEE may require additional formulas from advanced reference books (e.g., advanced electrochemistry, complex equilibrium). NEET Chemistry is primarily NCERT-based, so these formulas are sufficient. Always supplement with PYQ practice.