Classification of Elements and Periodicity in Properties — Revision Notes
NEET-UG · Chemistry
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Key Topics to Revise
Evolution of Periodic Classification
- Dobereiner's Triads: Elements arranged in groups of three with middle element's atomic weight as arithmetic mean of other two (Li-7, Na-23, K-39)
- Newland's Octave Law: Every eighth element had similar properties when arranged by increasing atomic weight
- Mendeleev's Periodic Law: Properties are periodic functions of atomic weights
Modern Periodic Table Structure
- 18 vertical groups (1-18) and 7 horizontal periods
- s-block: Groups 1-2 (alkali and alkaline earth metals)
- p-block: Groups 13-18 (metalloids, non-metals, noble gases)
Atomic and Ionic Radii
- Atomic radius decreases across period due to increasing nuclear charge
- Atomic radius increases down group due to addition of electron shells
- Covalent radius = half of internuclear distance in covalent bond
Ionization Energy and Electron Affinity
- IE increases across period (with exceptions for Group 2→3 and Group 5→6)
- IE decreases down group due to increased atomic size and shielding
- IE₁ < IE₂ < IE₃ due to increased effective nuclear charge
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