Chemical Kinetics
Jharkhand Board · Class 12 · Chemistry
All formulas from Chemical Kinetics in Jharkhand Board Class 12 Chemistry. Key equations, constants, and identities for board exam preparation.
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Rate of a Chemical Reaction
Average Rate = -Δ[R]/Δt = +Δ[P]/Δt
Instantaneous Rate = -d[R]/dt = +d[P]/dt
For aA + bB → cC + dD: Rate = -(1/a)d[A]/dt = -(1/b)d[B]/dt = (1/c)d[C]/dt = (1/d)d[D]/dt
Rate Law, Rate Constant, and Order of Reaction
Rate = k[A]ˣ[B]ʸ
Units of k = (mol L⁻¹)^(1-n) s⁻¹
Integrated Rate Equations
Zero Order: [R] = [R]₀ - kt OR k = ([R]₀ - [R])/t
First Order: ln[R] = -kt + ln[R]₀ OR k = (1/t) ln([R]₀/[R]) OR k = (2.303/t) log([R]₀/[R])
[R] = [R]₀ · e^(-kt)
Zero Order t₁/₂ = [R]₀ / 2k
First Order t₁/₂ = 0.693/k = ln2/k
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