Electrochemistry
Jammu & Kashmir Board · Class 12 · Chemistry
All formulas from Electrochemistry in Jammu & Kashmir Board Class 12 Chemistry. Key equations, constants, and identities for board exam preparation.
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2) Nernst Equation and Thermodynamics
E_(M^n+/M) = E_(M^n+/M)^0 - (RT/nF) ln(1/[M^n+])
E_(cell) = E_(cell)^0 - (RT/nF) ln Q
E_(cell) = E_(cell)^0 - (0.059/n) log Q
E^0_(cell) = (2.303RT/nF) log Kc
ΔrG = -nFE_(cell)
3) Conductance, Resistivity, Conductivity, Molar Conductivity
R = ρ l / A
G = 1/R = A/(ρl) = κA/l
G* = l/A = Rκ
Λm = κ/c
4) Variation of Molar Conductivity and Kohlrausch Law
Λm = Λm° - A c1/2
Λm° = ν+ λ+° + ν- λ-°
α = Λm / Λm°
Ka = cα2/(1-α)
Ka = cΛm2 / [Λm°(Λm° - Λm)]
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