Chemical Equilibrium
Maharashtra Board · Class 11 · Chemistry
Quick revision notes for Chemical Equilibrium — Maharashtra Board Class 11 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
Types of Chemical Reactions and Reversible Reactions
- Irreversible reactions proceed in one direction until reactants are exhausted (C + O₂ → CO₂)
- Reversible reactions occur in both forward and backward directions simultaneously (H₂ + I₂ ⇌ 2HI)
- Double arrow (⇌) indicates reversibility, single arrow (→) indicates irreversibility
Equilibrium in Physical Processes
- Liquid-vapour equilibrium: H₂O(l) ⇌ H₂O(g) in closed container
- Evaporation rate = condensation rate at equilibrium
- Solid-liquid equilibrium: ice and water at 273K in insulated system
Chemical Equilibrium and Law of Mass Action
- Chemical equilibrium occurs when rate of forward reaction = rate of reverse reaction
- Concentrations of all species remain constant at equilibrium
- Law of Mass Action: rate ∝ product of concentration terms raised to their stoichiometric coefficients
Homogeneous and Heterogeneous Equilibria
- Homogeneous equilibrium: all species in same phase (2HI(g) ⇌ H₂(g) + I₂(g))
- Heterogeneous equilibrium: species in different phases (CaCO₃(s) ⇌ CaO(s) + CO₂(g))
- For heterogeneous equilibria, concentrations of pure solids and liquids are constant
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