Principles Related to Practical Chemistry — Important Topics
NEET-UG · Chemistry
Most important topics from Principles Related to Practical Chemistry for NEET-UG Chemistry 2026 — high-weightage areas based on previous year analysis.
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Topics covered in Principles Related to Practical Chemistry for NEET-UG Chemistry.
Topics in Principles Related to Practical Chemistry
Detection of Elements in Organic Compounds
- Dumas Method for nitrogen: Organic compound + CuO → CO₂ + H₂O + N₂ + Cu. Nitrogen percentage = (28 × Volume of N₂ at NTP × 100)/(22400 × Weight of substance)
- Kjeldahl Method for nitrogen: Limited to compounds without azo (-N=N-), azoxy (-N=N→O), nitroso (-NO) groups and pyridine rings
- Carius Method for halogens: Compound heated with fuming HNO₃ and AgNO₃ in sealed tube forms AgX precipitate
Detection of Functional Groups
- Alcohols: Ceric ammonium nitrate test gives red coloration due to complex formation
- Phenols: Liebermann test (NaNO₂ + H₂SO₄) gives blue/green color; FeCl₃ gives violet color
- Aldehydes: Tollen's test (silver mirror), Fehling's test (red Cu₂O precipitate), Schiff's test (magenta color)
Preparation of Inorganic Compounds
- Mohr's Salt (FeSO₄.(NH₄)₂SO₄.6H₂O): Prepared by mixing equimolar amounts of FeSO₄.7H₂O and (NH₄)₂SO₄
- Reaction: FeSO₄.7H₂O + (NH₄)₂SO₄ → FeSO₄.(NH₄)₂SO₄.6H₂O + H₂O
- Potash Alum (K₂SO₄.Al₂(SO₄)₃.24H₂O): Prepared from equimolar K₂SO₄ and Al₂(SO₄)₃.18H₂O
Preparation of Organic Compounds
- Acetanilide: C₆H₅NH₂ + (CH₃CO)₂O → C₆H₅NHCOCH₃ + CH₃COOH
- p-Nitroacetanilide: Nitration of acetanilide using HNO₃/H₂SO₄ mixture (80% para, 20% ortho)
- Aniline Yellow: Coupling reaction between benzenediazonium chloride and aniline
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