Hydrocarbons
ICSE · Class 11 · Chemistry
All formulas from Hydrocarbons in ICSE Class 11 Chemistry. Key equations, constants, and identities for board exam preparation.
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1. Basic Classification and General Formulas
General formula of alkanes: CnH2n+2 [n = number of carbon atoms]
General formula of monocyclic cycloalkanes: CnH2n [n = number of carbon atoms in ring]
General formula of alkenes (one double bond): CnH2n [n = number of carbon atoms]
General formula of alkynes (one triple bond): CnH2n-2 [n = number of carbon atoms]
General formula of arenes with m rings: CnH2n-6m [n = carbon atoms, m = number of benzene rings]
2. Alkanes: Structure, Properties, and Preparation
sp3 hybrid orbitals in alkanes are at 109°28' directed to tetrahedron corners
Rotation around C-C single bond in alkanes is hindered by a small energy barrier of 1-20 kJ/mol due to torsional strain
Energy barrier to convert staggered ethane to eclipsed form is 12.5 kJ/mol
3. Methods of Preparation of Alkanes
C2H5Br + H2 -> C2H6 + HBr
R-Mg-X + H2O -> RH + Mg(OH)X
CH3OH + 2HI -> CH4 + I2 + H2O
CH3CHO + 4HI -> C2H6 + 2I2 + H2O
RCOONa + NaOH -> RH + Na2CO3
4. Chemical Reactions of Alkanes
CH4 + Cl2 -> CH3Cl + HCl
CH4 + I2 <-> CH3I + HI
CH4 + HNO3 -> CH3NO2 + H2O
C6H14 -> C6H13SO3H + H2O
CH3CH2OH -> CH2=CH2 + H2O
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