Thermodynamics
Madhya Pradesh Board · Class 11 · Chemistry
Quick revision notes for Thermodynamics — Madhya Pradesh Board Class 11 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
1. Basic thermodynamic terms
- The universe is composed of the system plus the surroundings.
- A system is that part of the universe in which observations are made.
- Surroundings mean everything other than the system.
2. Internal energy, heat, work, and the first law
- Internal energy is the total energy of the system, including chemical, electrical, and mechanical energy.
- Internal energy changes when heat is transferred, work is done, or matter enters or leaves the system.
- Work done on the system increases internal energy; work done by the system decreases it.
3. Work, pressure-volume work, and reversible processes
- In chemistry, the most common work is pressure-volume work.
- For expansion against constant external pressure, work is negative because the system does work on the surroundings.
- For compression, work is positive because work is done on the system.
4. Enthalpy and relation between ΔH and ΔU
- Enthalpy is a useful state function for reactions at constant pressure.
- Enthalpy is defined as H = U + pV.
- At constant pressure, heat absorbed by the system equals the enthalpy change.
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