Chemical Bonding and Molecular Structure
Madhya Pradesh Board · Class 11 · Chemistry
Quick revision notes for Chemical Bonding and Molecular Structure — Madhya Pradesh Board Class 11 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
1. Nature of Chemical Bond and Kössel-Lewis Approach
- A chemical bond is the attractive force that holds atoms, ions, or other constituents together in a chemical species.
- Kössel and Lewis independently gave a satisfactory electron-based explanation of bonding in 1916.
- Lewis pictured the atom as a positively charged Kernel with an outer shell that can hold a maximum of eight electrons.
2. Ionic or Electrovalent Bond and Lattice Enthalpy
- An ionic bond forms due to electrostatic attraction between positive and negative ions.
- Electrovalence is equal to the number of unit charges on the ion.
- Calcium has electrovalence +2 and chlorine has electrovalence -1.
3. Covalent Bond, Lewis Structures, Formal Charge, Resonance and Bond Parameters
- A covalent bond forms by sharing of electron pair(s) between atoms.
- A single covalent bond is formed when two atoms share one electron pair.
- A double bond is formed when two atoms share two pairs of electrons.
4. Polarity, Dipole Moment and Fajans' Rules
- A polar covalent bond has unequal sharing of electrons.
- Dipole moment is a vector quantity and depends on both bond polarity and molecular shape.
- Dipole moment is zero in symmetric molecules such as BeF2 and BF3 because bond dipoles cancel.
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