Electrochemistry — Formula Sheet
Punjab Board · Class 12 · Chemistry
6 formulas from Electrochemistry (Punjab Board Class 12 Chemistry) on one page, grouped by topic. Part of the Punjab Board Class 12 Chemistry syllabus.
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Formulas and Key Relations
Nernst Equation
General Nernst equation for a cell
E_cell = E°_cell – (RT/nF) ln Q
Conductance of Electrolytic Solutions
Resistance (R) of a conductor
R = ρl/A (in ohms, Ω); where ρ = resistivity, l = length, A = cross-section area.
Conductance (G) = 1/R = κA/l. SI unit: Siemens (S) or Ω⁻¹.
Variation of Molar Conductivity and Kohlrausch's Law
STRONG ELECTROLYTES (e.g., NaCl, KCl, HCl)
Λm increases SLOWLY with dilution. Debye-Hückel-Onsager equation: Λm = Λ°m – A√c (Debye-Hückel-Onsager or Kohlrausch equation).
Plot of Λm vs √c is a straight line for strong electrolytes. Intercept = Λ°m, Slope = –A.
Key relations
The Nernst equation relates electrode potential to concentration: E = E° - (RT/nF)ln(Q) or E = E° - (0.059/n)log(Q) at 298K.
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