The d-and f-Block Elements
CBSE · Class 12 · Chemistry
Summary of The d-and f-Block Elements for CBSE Class 12 Chemistry. Key concepts, important points, and chapter overview.
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The d-block contains the elements of Groups 3 to 12 in which d orbitals are progressively filled, while the f-block contains the 4f and 5f series placed separately at the bottom of the periodic table. Transition elements show metallic character, variable oxidation states, coloured ions, complex form
Key Concepts
The d
The d-block occupies the middle of the periodic table and includes four series: 3d, 4d, 5d, and 6d. The f-block contains the lanthanoids, 4f series fr
Transition metals are metals with
Transition metals are metals with an incomplete d subshell in the neutral atom or in one of their ions. Scandium is a transition element because its g
The general outer configuration is (n
The general outer configuration is (n-1)d1-10ns1-2, but chromium has 3d5 4s1, copper has 3d10 4s1, and palladium has 4d10 5s0. These exceptions occur
Transition metals are hard
Transition metals are hard, lustrous, dense, and have high melting and boiling points. Melting points generally rise to a maximum near the middle of t
Ionisation enthalpies increase across a series
Ionisation enthalpies increase across a series, but not smoothly. Exchange energy, d5 stability, and subshell stability cause irregularities. Mn+ and
Learning Objectives
- Understand the position of d- and f-block elements in the periodic table.
- Identify the electronic configurations of transition and inner transition elements.
- Explain why some elements are transition elements and others are not.
- Relate oxidation states and electrode potentials to stability and reactivity.
- Describe the preparation, properties, and uses of potassium dichromate and potassium permanganate.
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Sources & Official References
- NCERT Official — ncert.nic.in
- CBSE Academic — cbseacademic.nic.in
- CBSE Official — cbse.gov.in
- National Education Policy 2020 — education.gov.in
Content is aligned to the official syllabus. Refer to the board website for the latest curriculum.
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