Chemical Thermodynamics
Maharashtra Board · Class 12 · Chemistry
Quick revision notes for Chemical Thermodynamics — Maharashtra Board Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
Basic Terms and Definitions in Thermodynamics
- System: Part of universe under thermodynamic investigation (e.g., gas in a cylinder)
- Surroundings: Everything outside the system in the universe
- Open System: Exchanges both matter and energy (hot coffee in open cup)
Types of Thermodynamic Processes
- Isothermal Process: Temperature constant (ΔT = 0, ΔU = 0 for ideal gas)
- Isobaric Process: Pressure constant (ΔP = 0, occurs at atmospheric pressure)
- Isochoric Process: Volume constant (ΔV = 0, reactions in closed containers)
Work and Heat in Thermodynamics
- Work (W): Energy transfer due to organized motion, measured in Joules
- Heat (Q): Energy transfer due to temperature difference, measured in Joules
- Sign Convention: +W (work done on system), -W (work done by system)
Internal Energy and First Law of Thermodynamics
- Internal Energy (U): Total energy stored in a system, state function
- First Law: Energy cannot be created or destroyed, only converted
- Mathematical form: ΔU = Q + W
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