Elements of Groups 16, 17 and 18
Maharashtra Board · Class 12 · Chemistry
Quick revision notes for Elements of Groups 16, 17 and 18 — Maharashtra Board Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
Electronic Configuration and General Properties
- Group 16: ns²np⁴ (need 2 electrons to complete octet)
- Group 17: ns²np⁵ (need 1 electron to complete octet)
- Group 18: ns²np⁶ (complete octet, chemically inert)
Anomalous Behavior of First Elements
- Oxygen anomalies: diatomic (O₂), paramagnetic, shows -2, -1, +2 oxidation states only
- H₂O is liquid due to hydrogen bonding while other hydrides are gases
- Fluorine anomalies: highest electronegativity, shows only -1 oxidation state
Chemical Reactivity and Oxidation States
- Group 16: Common oxidation states -2, +2, +4, +6 (except O: -2, -1, +2)
- Group 17: F shows -1 only; others show -1, +1, +3, +5, +7
- Group 18: Generally zero valent; Xe shows +2, +4, +6, +8
Allotropy and Important Compounds
- Sulfur allotropes: Rhombic (α-S₈, stable <369K) and Monoclinic (β-S₈, stable >369K)
- Both have S₈ puckered ring structure
- Ozone (O₃): Angular molecule, powerful oxidizing agent, protects from UV rays
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