Aldehydes, Ketones and Carboxylic Acids
Maharashtra Board · Class 12 · Chemistry
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Key Topics to Revise
Classification and Structure
- Carbonyl group (C=O) is the functional group common to aldehydes and ketones
- Aldehydes: -CHO group (formyl group) attached to at least one hydrogen
- Ketones: C=O group attached to two alkyl/aryl groups (ketonic carbonyl)
Nomenclature
- IUPAC names: Aldehydes end in '-al', ketones in '-one', acids in '-oic acid'
- Aldehydes: Replace 'e' of alkane with 'al' (methanal, ethanal, propanal)
- Ketones: Replace 'e' of alkane with 'one', number from nearest end to C=O
Preparation Methods
- Oxidation of alcohols: Primary alcohols → aldehydes, Secondary alcohols → ketones
- Dehydrogenation: Alcohols over Cu at 573K give aldehydes/ketones
- Ozonolysis: Alkenes with O₃ followed by Zn/H₂O give carbonyl compounds
Physical Properties
- Polar C=O bond leads to dipole-dipole interactions
- Lower aldehydes/ketones are water-soluble due to hydrogen bonding
- Boiling points increase with molecular mass due to stronger van der Waals forces
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