Chemical Kinetics — Concept Maps
Madhya Pradesh Board · Class 12 · Chemistry
4 concept maps of Chemical Kinetics for Madhya Pradesh Board Class 12 Chemistry, each also written out as a text outline.
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Chemical Kinetics - Complete Chapter Mind Map
The map in words
- Chemical Kinetics
- Rate of Reaction
- Average Rate
- Change in conc over time
- r = delta-C / delta-t
- Instantaneous Rate
- Slope of tangent
- r = -d-R / dt
- Units
- mol per L per s
- atm per s for gases
- Average Rate
- Factors Affecting Rate
- Concentration
- Rate increases with conc
- Rate law expression
- Temperature
- Rate doubles per 10 degree rise
- Arrhenius equation
- Catalyst
- Lowers activation energy
- Alternate pathway
- Pressure
- For gaseous reactions
- Concentration
- Rate Law
- Rate = k times A^x times B^y
- x and y from experiment
- Not from stoichiometry
- Rate Constant k
- Proportionality factor
- Specific to reaction
- Temperature dependent
- Order of Reaction
- Zero order
- First order
- Second order
- Fractional order
- Molecularity
- Unimolecular
- Bimolecular
- Termolecular
- Only elementary reactions
- Rate = k times A^x times B^y
- Integrated Rate Equations
- Zero Order
- R = R0 minus kt
- t-half = R0 divided by 2k
- Plot R vs t is linear
- First Order
- ln-R = minus-kt + ln-R0
- t-half = 0.693 divided by k
- Plot ln-R vs t is linear
- Independent of initial conc
- Pseudo First Order
- One reactant in excess
- Ethyl acetate hydrolysis
- Inversion of cane sugar
- Zero Order
- Temperature Dependence
- Arrhenius Equation
- k = A times e^minus-Ea by RT
- Activation Energy Ea
- Energy for activated complex
- Barrier to reaction
- Frequency Factor A
- Pre-exponential factor
- Collision frequency
- Maxwell-Boltzmann Distribution
- Energy distribution in molecules
- Area beyond Ea gives fraction
- Arrhenius Equation
- Collision Theory
- Collision Frequency Z
- Effective Collisions
- Sufficient energy
- Proper orientation
- Steric Factor P
- Probability factor
- Orientation requirement
- Rate = P times Z-AB times e^minus-Ea by RT
- Rate of Reaction
Chemical Kinetics — Complete Chapter Overview
The map in words
- Chemical Kinetics
- Rate of Reaction
- Average Rate
- Instantaneous Rate
- Units mol per L per s
- Factors Affecting Rate
- Concentration
- Temperature
- Catalyst
- Pressure for gases
- Rate Law
- Rate Expression
- Rate Constant k
- Order of Reaction
- Molecularity
- Integrated Rate Equations
- Zero Order
- kt equals R0 minus R
- t half equals R0 by 2k
- First Order
- k equals 2.303 by t log R0 by R
- t half equals 0.693 by k
- Zero Order
- Temperature Dependence
- Arrhenius Equation
- k equals A times e to Ea by RT
- Activation Energy Ea
- Frequency Factor A
- Graphical Method
- ln k vs 1 by T
- Arrhenius Equation
- Collision Theory
- Collision Frequency Z
- Threshold Energy
- Steric Factor P
- Effective Collisions
- Rate of Reaction
Chemical Kinetics — Complete Concept Map
The map in words
- Chemical Kinetics
- Rate of Reaction
- Average Rate
- Change in conc over time
- Units mol per L per s
- Instantaneous Rate
- Slope of tangent
- at specific time t
- Average Rate
- Factors Affecting Rate
- Concentration
- Rate Law
- Rate Constant k
- Temperature
- Arrhenius Equation
- Activation Energy Ea
- Catalyst
- Lowers Ea
- Alt pathway
- Pressure
- For gaseous reactions
- Concentration
- Order of Reaction
- Zero Order
- Rate independent of conc
- t half = R0 by 2k
- First Order
- Rate proportional to conc
- t half = 0.693 by k
- Fractional Order
- eg CHCl3 plus Cl2
- Zero Order
- Molecularity
- Unimolecular
- Bimolecular
- Trimolecular
- Only for elementary steps
- Integrated Rate Laws
- Zero Order
- R = R0 minus kt
- First Order
- ln R = minus kt plus ln R0
- Zero Order
- Collision Theory
- Collision Frequency Z
- Steric Factor P
- Effective Collisions
- Sufficient energy
- Proper orientation
- Rate of Reaction
Study of reaction rates and reaction mechanisms
The map in words
- Study of reaction rates and reaction mechanisms
- Rate of reaction
- Rate law
- Order of reaction
- Molecularity
- Elementary and complex reactions
- Integrated rate equations
- Temperature dependence
- Collision theory
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