Chemical Kinetics
Madhya Pradesh Board · Class 12 · Chemistry
Quick revision notes for Chemical Kinetics — Madhya Pradesh Board Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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1. Rate of a Chemical Reaction
- Rate of reaction means the change in concentration of reactant or product per unit time.
- Rate can be written as rate of disappearance of reactant or rate of appearance of product.
- Average rate is measured over a time interval and cannot predict the rate at one exact instant.
2. Rate Law, Rate Constant, and Order of Reaction
- Rate law is the relation between rate and concentrations of reactants raised to powers.
- The powers in the rate law are determined experimentally and may or may not match stoichiometric coefficients.
- Rate constant k is the proportionality constant in the rate law.
3. Elementary Reactions, Complex Reactions, Molecularity, and Rate Determining Step
- An elementary reaction takes place in one step.
- A complex reaction occurs through a sequence of elementary steps, called a mechanism.
- Molecularity is the number of reacting species colliding simultaneously in an elementary reaction.
4. Integrated Rate Equations and Half-Life
- Integrated rate equations connect concentration and time directly.
- Zero order reactions show a linear decrease of concentration with time.
- First order reactions show exponential decay of concentration with time.
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