Ionic Equilibrium — Concept Maps
Tamil Nadu Board · Class 12 · Chemistry
3 concept maps of Ionic Equilibrium for Tamil Nadu Board Class 12 Chemistry, each also written out as a text outline.
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Ionic Equilibrium – Complete Chapter Overview
The map in words
- Ionic Equilibrium
- Acid-Base Theories
- Arrhenius Theory
- Acid gives H+ in water
- Base gives OH- in water
- Limited to aqueous only
- Bronsted-Lowry Theory
- Acid is proton donor
- Base is proton acceptor
- Conjugate acid-base pairs
- Explains NH3 as base
- Lewis Theory
- Acid accepts electron pair
- Base donates electron pair
- BF3 AlCl3 as Lewis acids
- NH3 H2O as Lewis bases
- Arrhenius Theory
- Ionisation of Water
- Kw = H3O+ times OH- = 10 to -14
- At 25 degrees C
- Increases with temperature
- Neutral solution pH = 7
- pH Scale
- pH = -log H3O+
- pOH = -log OH-
- pH + pOH = 14
- Acidic pH less than 7
- Basic pH greater than 7
- Weak Acids and Bases
- Partial dissociation
- Ka and Kb constants
- Ostwald Dilution Law
- alpha increases on dilution
- alpha = sqrt Ka by C
- H+ = sqrt Ka times C
- Common Ion Effect
- Suppresses dissociation
- Le Chatelier principle
- Basis of buffers
- Buffer Solutions
- Acidic buffer
- Weak acid plus its salt
- Example CH3COOH plus CH3COONa
- Basic buffer
- Weak base plus its salt
- Example NH4OH plus NH4Cl
- Henderson Hasselbalch equation
- pH = pKa + log salt by acid
- pOH = pKb + log salt by base
- Buffer capacity beta = dB by dpH
- Acidic buffer
- Salt Hydrolysis
- Strong acid + Strong base
- No hydrolysis
- pH = 7
- Strong base + Weak acid
- Anionic hydrolysis
- pH greater than 7
- pH = 7 + half pKa + half logC
- Strong acid + Weak base
- Cationic hydrolysis
- pH less than 7
- pH = 7 - half pKb - half logC
- Weak acid + Weak base
- Both ions hydrolyse
- pH = 7 + half pKa - half pKb
- Strong acid + Strong base
- Solubility Product
- Ksp = product of ion concentrations
- Molar solubility s
- AB type Ksp = s squared
- AB2 type Ksp = 4s cubed
- Ionic product vs Ksp
- IP greater than Ksp precipitate forms
- IP less than Ksp no precipitate
- IP = Ksp saturated
- Acid-Base Theories
Ionic Equilibrium - Concepts Hierarchy
The map in words
- Ionic Equilibrium
- Acid-Base Concepts
- Arrhenius Concept
- H+ Donor
- OH- Acceptor
- Lowry-Bronsted Theory
- Proton Donor
- Proton Acceptor
- Conjugate Pairs
- Lewis Concept
- Electron Pair Acceptor
- Electron Pair Donor
- Arrhenius Concept
- Water Equilibrium
- Auto-ionization
- Kw Constant
- pH Scale
- pOH Scale
- Weak Acid Ionization
- Ka Constant
- Degree of Dissociation
- Ostwald's Law
- Auto-ionization
- Equilibrium Solutions
- Buffer Solutions
- Acidic Buffers
- Basic Buffers
- Henderson-Hasselbalch
- Salt Hydrolysis
- Anionic Type
- Cationic Type
- Mixed Type
- Buffer Solutions
- Precipitation
- Solubility Product
- Ksp Calculation
- Ionic Product
- Molar Solubility
- Common Ion Effect
- Equilibrium Shift
- Reduced Solubility
- Solubility Product
- Acid-Base Concepts
Overview of Ionic Equilibrium - Key Topics
The map in words
- Ionic Equilibrium
- Acid Base Theories
- Arrhenius
- Acid gives H plus
- Base gives OH minus
- Only in water
- Bronsted Lowry
- Acid is proton donor
- Base is proton acceptor
- Conjugate pairs
- Lewis
- Acid accepts electron pair
- Base donates electron pair
- Most general
- Arrhenius
- Ionic Product of Water
- Kw equals H3O plus times OH minus
- Kw at 25C equals 10 power minus 14
- Increases with temperature
- pH plus pOH equals 14
- Weak Electrolytes
- Dissociation constant Ka or Kb
- Degree of dissociation alpha
- Ostwalds Dilution Law
- alpha equals root Ka over C
- Buffer Solutions
- Acidic Buffer
- Weak acid plus its salt
- Example CH3COOH plus CH3COONa
- Basic Buffer
- Weak base plus its salt
- Example NH4OH plus NH4Cl
- Henderson Hasselbalch
- pH equals pKa plus log salt over acid
- Acidic Buffer
- Salt Hydrolysis
- Strong acid Strong base
- Neutral pH 7
- Strong base Weak acid
- Basic pH greater than 7
- Strong acid Weak base
- Acidic pH less than 7
- Weak acid Weak base
- Depends on Ka vs Kb
- Strong acid Strong base
- Solubility Product
- Ksp equals product of ionic concentrations
- Molar solubility s
- Ionic Product vs Ksp
- Precipitation prediction
- Acid Base Theories
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