Equilibrium
ICSE · Class 11 · Chemistry
Quick revision notes for Equilibrium — ICSE Class 11 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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1. Physical and Chemical Equilibrium
- A large number of chemical reactions do not go to completion and attain a state of equilibrium after some time.
- Equilibrium is dynamic: both forward and backward processes continue at the same rate.
- The symbol for equilibrium is ⇌, read as reversible arrow.
2. Henry's Law and Dissolution of Gases
- Henry's Law was given by William Henry in 1803.
- The mass of a gas dissolved in a given mass of solvent is proportional to the pressure of the gas at equilibrium, provided the gas does not undergo chemical change.
- Henry's law applies only to ideal gases, or real gases at low pressure.
3. Law of Mass Action, Equilibrium Constant, and Reaction Quotient
- Law of mass action was given by Guldberg and Waage in 1864.
- At constant temperature, the rate of a chemical reaction is directly proportional to the product of active masses of reacting species, each raised to its stoichiometric coefficient.
- Equilibrium constant expresses the ratio of product active masses to reactant active masses at equilibrium.
4. Types of Chemical Equilibria
- Homogeneous equilibrium means all reactants and products are in the same phase.
- Heterogeneous equilibrium means reactants and products are in different phases.
- Examples of homogeneous equilibria include H2(g) + I2(g) ⇌ 2HI(g), 2SO2(g) + O2(g) ⇌ 2SO3(g), and CH3COOH(l) + C2H5OH(l) ⇌ CH3COOC2H5(l) + H2O(l).
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