Chemical Thermodynamics
ICSE · Class 11 · Chemistry
Quick revision notes for Chemical Thermodynamics — ICSE Class 11 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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1. Basic Ideas: System, Surroundings, and Types of Systems
- A system is the specific part of the universe under study with fixed boundaries.
- The surroundings are the rest of the universe other than the system.
- Open systems exchange both matter and energy with the surroundings.
2. First Law of Thermodynamics and Internal Energy
- The first law of thermodynamics is the law of conservation of energy.
- Energy can neither be created nor destroyed, only converted from one form to another.
- Internal energy U or E is the total energy associated with a fixed amount of a substance under given conditions.
3. Pressure-Volume Work and Reversible or Irreversible Expansion
- Pressure-volume work occurs when the system and surroundings are at different pressures.
- For expansion of a gas, work done by the system is negative.
- For contraction of a gas, work done on the system is positive.
4. Enthalpy and Heat Changes at Constant Pressure
- Enthalpy H is the total heat content of a system at constant pressure.
- H = U + PV.
- Enthalpy is a state function.
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