Electrochemistry
ICSE · Class 12 · Chemistry
Quick revision notes for Electrochemistry — ICSE Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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1. Basic Ideas and Types of Electrochemical Cells
- Electrochemistry is the branch of chemistry that studies conversion of chemical energy into electrical energy and vice versa.
- An electrochemical cell is a device that can convert chemical energy into electrical energy or vice versa.
- Galvanic cells or voltaic cells convert chemical energy into electrical energy through a spontaneous redox reaction.
2. Construction and Representation of a Galvanic Cell
- A galvanic cell has two half cells: one oxidation half cell and one reduction half cell.
- The oxidation electrode is written on the left and the reduction electrode on the right in cell representation.
- A single vertical line separates phases, and double vertical lines show a salt bridge.
3. Electrode Potential and Standard Hydrogen Electrode
- Electrode potential is the tendency of an electrode to lose or gain electrons when it is in contact with its own ions in solution.
- If metal atoms lose electrons, oxidation potential develops and the electrode becomes negative.
- If metal ions gain electrons, reduction potential develops and the electrode becomes positive.
4. Electrochemical Series and Its Applications
- The electrochemical series is the arrangement of electrode systems in increasing order of their standard reduction potentials.
- Higher reduction potential means greater tendency to get reduced.
- Lower reduction potential means greater tendency to get oxidised.
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