Aldehydes, Ketones and Carboxylic Acids
ICSE · Class 12 · Chemistry
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1. Carbonyl Group and Basic Reactivity
- The carbonyl group contains a carbon atom double bonded to oxygen.
- The carbon atom of the carbonyl group is sp2 hybridised.
- The carbonyl group is polar because oxygen is more electronegative than carbon.
2. Important Reactions of Aldehydes and Ketones
- Aldehydes and ketones react with hydrogen cyanide to form cyanohydrins.
- They react with ammonia and its derivatives to form addition products and then elimination products.
- They react with sodium bisulphite to form bisulphite addition compounds in many cases.
3. Preparation of Carboxylic Acids
- Primary alcohols and aldehydes can be oxidised to carboxylic acids by oxidising agents such as potassium permanganate and potassium dichromate.
- Aldehydes can also be oxidised by mild oxidising agents like Tollens' reagent.
- Nitriles on hydrolysis with acid or alkali give carboxylic acids.
4. Physical Properties of Carboxylic Acids
- Lower carboxylic acids up to C4 are highly soluble in water.
- Acids with seven or more carbon atoms are practically insoluble in water.
- C4 to C9 acids are oily liquids with a goat-like odour.
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