Spontaneity Of Chemical Reactions
NIOS · Class 12 · Chemistry
Complete topic list for Spontaneity Of Chemical Reactions in NIOS Class 12 Chemistry. Key concepts, sub-topics, and what to focus on for board exams.
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Topics in Spontaneity Of Chemical Reactions
1. Spontaneous and Non-Spontaneous Processes
- A spontaneous process occurs naturally without external intervention once initiated
- Non-spontaneous processes require continuous external energy input to proceed
- Examples of spontaneous processes: cooling of hot water, rusting of iron, mixing of gases, melting of ice below 0°C
2. Entropy and Disorder
- Entropy (S) is a measure of disorder, randomness, or microstates in a system
- Greater disorder in a system means higher entropy
- Crystalline solids have the lowest entropy (most ordered)
3. The Second Law of Thermodynamics
- The second law states: all spontaneous processes increase the entropy of the universe
- For a spontaneous process: ΔS_universe = ΔS_system + ΔS_surroundings > 0
- At equilibrium: ΔS_universe = 0 (no net change)
4. The Third Law of Thermodynamics
- The third law states: the entropy of a pure, perfectly crystalline solid at absolute zero (0 K) is zero
- This provides a reference point (entropy zero) from which all other entropy values are measured
- Allows calculation of absolute entropy values for substances at any temperature above 0 K
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