Spontaneity Of Chemical Reactions — Concept Maps
NIOS · Class 12 · Chemistry
3 concept maps of Spontaneity Of Chemical Reactions for NIOS Class 12 Chemistry, each also written out as a text outline.
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Complete Mind Map: Spontaneity of Chemical Reactions
The map in words
- Spontaneity of Reactions
- Spontaneous Process
- Occurs naturally
- No external agency needed
- Unidirectional
- Examples
- Rusting of iron
- Mixing of gases
- Cooling of hot water
- Non-Spontaneous Process
- Needs external energy
- Reverse of spontaneous
- Entropy S
- Measure of disorder
- Unit J per K per mol
- Delta S = q_rev divided by T
- Order
- Solid lowest
- Liquid middle
- Gas highest
- Increases with temperature
- Second Law
- Delta S_universe greater than 0
- Spontaneous
- Delta S_universe equals 0
- Equilibrium
- Third Law
- Perfect crystal at 0K
- S equals zero
- Gives absolute entropy
- Gibbs Energy G
- G = H minus TS
- Delta G = Delta H minus T Delta S
- Delta G less than 0 spontaneous
- Delta G equals 0 equilibrium
- Delta G greater than 0 non-spontaneous
- Standard Gibbs Energy
- Delta r G0 from Delta f G0
- Delta r G0 = minus RT ln K
- Large K gives negative Delta r G0
- Spontaneous Process
Complete Overview of Spontaneity of Chemical Reactions
The map in words
- Spontaneity of Chemical Reactions
- Fundamental Concepts
- Spontaneous Process
- No external intervention
- Natural direction
- Examples rusting
- Non-Spontaneous Process
- Requires external energy
- Artificial processes
- Examples electrolysis
- First Law Limitation
- Energy conservation
- No spontaneity criterion
- Spontaneous Process
- Entropy Concept
- Definition
- Disorder measure
- Randomness in system
- Microstates count
- State of Matter
- Solid lowest entropy
- Liquid intermediate
- Gas highest entropy
- Calculation
- Phase transitions
- Chemical reactions
- Temperature dependence
- Third Law
- Zero at absolute zero
- Absolute entropy values
- Reference point
- Definition
- Thermodynamic Laws
- Second Law
- Universe entropy increases
- ΔS_univ greater than zero
- Spontaneity criterion
- Third Law
- Perfect crystal at 0K
- Entropy equals zero
- Absolute values possible
- Second Law
- Gibbs Energy
- Definition
- G equals H minus TS
- State function
- Combines factors
- Spontaneity Criterion
- Negative ΔG spontaneous
- Zero ΔG equilibrium
- Positive ΔG non-spontaneous
- Temperature Dependence
- Four ΔH ΔS cases
- Transition points
- Low vs high temperature
- Definition
- Calculations
- ΔG from ΔH and ΔS
- Formula ΔG=ΔH-TΔS
- Temperature effects
- Sign interpretation
- Standard Values
- Formation values
- Reaction ΔG calculated
- Tables available
- Equilibrium Link
- ΔG equals minus RT ln K
- Large K spontaneous
- Equilibrium position
- ΔG from ΔH and ΔS
- Fundamental Concepts
Spontaneity of Chemical Reactions: Concept Overview
The map in words
- Spontaneity of Chemical Reactions
- Fundamental Concepts
- Spontaneous Processes
- Occur naturally
- No external input
- Irreversible
- Non-Spontaneous Processes
- Require external work
- Driven by outside agency
- Reverse is spontaneous
- Spontaneous Processes
- Entropy S
- Measure of disorder
- Solid < Liquid < Gas
- Increases with heating
- Third Law reference
- Thermodynamic Laws
- First Law
- Energy conservation
- Does not determine spontaneity
- Second Law
- Delta S universe > 0
- Directs all processes
- Third Law
- S = 0 at 0 K
- Absolute entropy values
- First Law
- Gibbs Energy
- Equation ΔG = ΔH - TΔS
- System-focused criterion
- Temperature dependent
- Combines H and S factors
- Spontaneity Criteria
- ΔG < 0 Spontaneous
- ΔG = 0 Equilibrium
- ΔG > 0 Non-spontaneous
- Equilibrium Constant
- ΔG° = -RT ln K
- Links thermodynamics
- K >> 1 products favored
- K << 1 reactants favored
- Fundamental Concepts
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