Coordination Compounds
Madhya Pradesh Board · Class 12 · Chemistry
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1. Werner's Theory and Basic Terms
- Alfred Werner first formulated the theory of coordination compounds.
- Werner proposed two types of valence: primary valence and secondary valence.
- Primary valence is ionisable and is satisfied by negative ions.
2. Ligands, Denticity, and Chelation
- Ligands may be simple ions, small molecules, or large molecules.
- Unidentate ligands bind through one donor atom.
- Didentate ligands bind through two donor atoms.
3. Nomenclature of Coordination Compounds
- The formula of a coordination compound is written with the metal first, then ligands in alphabetical order.
- The whole coordination entity is enclosed in square brackets.
- When the coordination entity is charged, the charge is written outside the brackets as a right superscript.
4. Isomerism in Coordination Compounds
- Isomers have the same chemical formula but different arrangement of atoms.
- Coordination compounds show stereoisomerism and structural isomerism.
- Stereoisomerism includes geometrical and optical isomerism.
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