Coordination Compounds
Madhya Pradesh Board · Class 12 · Chemistry
Summary of Coordination Compounds for Madhya Pradesh Board Class 12 Chemistry. Key concepts, important points, and chapter overview.
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Coordination compounds are formed when a metal atom or ion is surrounded by ions or neutral molecules called ligands. Their study explains bonding, geometry, colour, magnetic behaviour, isomerism, and many important uses in chemistry, biology, metallurgy, medicine, and industry. Werner’s theory gave
Key Concepts
Werner proposed that metals in coordination
Werner proposed that metals in coordination compounds show primary valence and secondary valence. Primary valence is ionisable and is satisfied by neg
A coordination entity is a central
A coordination entity is a central metal atom or ion bonded to a fixed number of ligands. The species inside square brackets forms the coordination sp
Ligands are ions or molecules attached
Ligands are ions or molecules attached to the central metal atom or ion. They may be unidentate, didentate, polydentate, chelate, or ambidentate. EDTA
Coordination number is the number
Coordination number is the number of ligand donor atoms directly bonded to the metal through sigma bonds. Common coordination polyhedra are octahedral
In naming coordination compounds
In naming coordination compounds, ligands are written before the metal name in alphabetical order, oxidation state is shown in Roman numerals, and ani
Learning Objectives
- Understand Werner’s theory and its postulates
- Define coordination entity, ligand, coordination number, coordination sphere, coordination polyhedron, oxidation number, homoleptic complex, and heteroleptic complex
- Write formulas and names of mononuclear coordination compounds
- Identify and explain different types of isomerism in coordination compounds
- Understand bonding in coordination compounds using Valence Bond Theory and Crystal Field Theory
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