Organic Nitrogen Compounds — Formula Sheet
Tamil Nadu Board · Class 12 · Chemistry
6 formulas from Organic Nitrogen Compounds (Tamil Nadu Board Class 12 Chemistry) on one page, grouped by topic.
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Formulas and Key Relations
1.5-13.1.8 Preparation and Properties of Nitro Compounds
CH₃CH₂-Br + KNO₂ → CH₃CH₂-NO₂ + KBr (follows SN2 mechanism)
INDUSTRIAL PREPARATION
Vapor-phase nitration at 675K - methane + HNO₃ → nitromethane + H₂O
2.3-13.2.5 Preparation Methods of Amines
METHOD 1 - REDUCTION OF NITRO COMPOUNDS
Nitroalkanes/nitroarenes + H₂/Ni (or Sn/HCl or Pd/H₂) → Primary amines
CH₃CH₂-NO₂ + 6[H] → CH₃CH₂-NH₂ + 2H₂O (using Ni catalyst with H₂)
METHOD 2 - REDUCTION OF NITRILES
R-CN + 4[H] → R-CH₂-NH₂ (using LiAlH₄ or Na/C₂H₅OH)
Key relations
Primary and secondary nitroalkanes exhibit tautomerism between the nitro form (R-NO₂) and the aci-form (R-N(OH)=O).
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