Surface Chemistry
Tamil Nadu Board · Class 12 · Chemistry
Complete topic list for Surface Chemistry in Tamil Nadu Board Class 12 Chemistry. Key concepts, sub-topics, and what to focus on for board exams.
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Topics in Surface Chemistry
1. Adsorption and Absorption
- Adsorption is a SURFACE phenomenon where molecules concentrate at the interface between two phases
- Absorption is a BULK phenomenon where molecules are distributed throughout the adsorbent
- Adsorbent: material on which adsorption occurs (charcoal, silica gel, metals like Ni, Cu, Pt)
2. Classification of Adsorption
- PHYSICAL ADSORPTION (Physisorption/Van der Waals Adsorption):
- • Weak van der Waals forces (dipole-dipole, dispersion forces)
- • Heat of adsorption: ~4-40 kJ/mol (LOW)
3. Factors Affecting Adsorption
- SURFACE AREA OF ADSORBENT: Higher surface area → higher adsorption (directly proportional)
- • Powdered form more effective than bulk
- • Explains why finely divided catalysts are more effective
4. Applications of Adsorption
- GAS MASKS: Activated charcoal used in WWI and WWII—adsorbs toxic gases
- CREATING HIGH VACUUM: Activated charcoal used in vessels (Tail and Dewar method)
- DRYING OF GASES: Alumina, silica gel for drying CO₂, N₂, Cl₂, O₂, He; silica gel in blast furnaces
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