Analytical chemistry — Revision Notes
ICSE · Class 10 · Chemistry
Analytical chemistry revision notes for ICSE Class 10 Chemistry: 4 topics in quick points. Part of the ICSE Class 10 Chemistry syllabus.
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1. Basics of Analytical Chemistry
- Analytical chemistry deals with qualitative and quantitative analysis.
- Qualitative analysis determines the nature and quality of the substance under examination.
- Quantitative analysis determines the constituents of a chemical substance or mixture.
2. Action of Ammonium Hydroxide on Salt Solutions
- Ammonium hydroxide is used for precipitation of metal cations as hydroxides, formation of complex salts, making the medium weakly basic, and providing ammonia.
- Precipitation means formation of an insoluble substance when two or more solutions are mixed.
- Some precipitated metallic hydroxides become soluble in excess ammonium hydroxide because of complex salt formation.
3. Action of Sodium Hydroxide on Salt Solutions
- Sodium hydroxide is mainly used for precipitation of insoluble hydroxides from metallic salt solutions.
- Some precipitated metallic hydroxides dissolve in excess NaOH to form soluble complex salts.
- Calcium salt solutions give dull white Ca(OH)2 precipitate with NaOH, insoluble in excess.
4. Action of Caustic Alkalis on Metals
- Caustic alkalis such as NaOH and KOH react with some metals and their oxides.
- Zinc dissolves in hot and concentrated caustic alkalis to form colourless soluble zincates with hydrogen gas evolution.
- Aluminium reacts with boiling caustic alkalis to form colourless aluminates with hydrogen gas evolution.
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