Haloalkanes and Haloarenes — Chapter Summary
Madhya Pradesh Board · Class 12 · Chemistry
Summary of Haloalkanes and Haloarenes for Madhya Pradesh Board Class 12 Chemistry. Part of the Madhya Pradesh Board Class 12 Chemistry syllabus.
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Overview
Haloalkanes and haloarenes are halogenated organic compounds in which hydrogen atoms of hydrocarbons are replaced by halogen atoms. Haloalkanes contain halogen attached to an sp3 hybridised carbon of an alkyl group, while haloarenes contain halogen directly attached to an sp2 hybridised carbon of an
Key Concepts
Halogenated compounds are classified as mono
Halogenated compounds are classified as mono-, di-, or polyhalogen compounds depending on the number of halogen atoms. They may also be grouped as alk
Haloalkanes have halogen attached to sp3
Haloalkanes have halogen attached to sp3 carbon of an alkyl group. Haloarenes have halogen attached directly to sp2 carbon of an aromatic ring. Haloar
Haloalkanes are prepared from alcohols using
Haloalkanes are prepared from alcohols using HCl/ZnCl2, NaBr/H2SO4, phosphorus trihalides, and thionyl chloride. They can also be formed from alkenes
Haloarenes are prepared mainly by electrophilic
Haloarenes are prepared mainly by electrophilic substitution of arenes with halogens in the presence of Lewis acid catalysts, and by Sandmeyer-type re
The carbon
The carbon-halogen bond is polar because halogens are more electronegative than carbon. Bond length increases from C-F to C-I in alkyl halides. In hal
Learning Objectives
- Classify haloalkanes and haloarenes by number of halogen atoms and by the type of carbon-halogen bond.
- Write common and IUPAC names of haloalkanes and haloarenes.
- Explain methods of preparation of haloalkanes and haloarenes.
- Relate structure to physical properties such as boiling point, melting point, density, and solubility.
- Understand nucleophilic substitution through SN1 and SN2 mechanisms.
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