d-block and f-block Elements — Chapter Summary
Telangana Open School (TOSS) · Class 12 · Chemistry
Summary of d-block and f-block Elements for Telangana Open School (TOSS) Class 12 Chemistry. This chapter explores the chemistry of d-block and f-block.
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Overview
This chapter explores the chemistry of d-block and f-block elements, which occupy the middle and bottom sections of the periodic table. These elements, especially the transition metals, exhibit unique properties such as variable oxidation states, formation of colored compounds, and catalytic activit
Key Concepts
Transition elements are those in
Transition elements are those in which the d-orbitals are partially filled in either the atomic or ionic state. They include elements from groups 3 to
Due to the small energy difference
Due to the small energy difference between (n-1)d and ns orbitals, transition metals can use both for bonding, leading to multiple oxidation states. F
The steady decrease in atomic
The steady decrease in atomic and ionic radii across the lanthanide series due to poor shielding by 4f electrons. This causes elements like zirconium
Transition metal ions are often colored
Transition metal ions are often colored due to d-d transitions when light is absorbed. They also show paramagnetism when unpaired electrons are presen
Transition metals act as catalysts due
Transition metals act as catalysts due to variable oxidation states and form complexes because of small size, high charge, and vacant d-orbitals. Exam
Learning Objectives
- Define transition metals and write their electronic configurations
- List general and characteristic properties of transition elements
- Explain variable oxidation states, magnetic properties, and complex formation
- Recall the preparation of potassium permanganate and potassium dichromate
- Write chemical equations for oxidizing actions in different media
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