Chemical Kinetics
Tamil Nadu Board · Class 12 · Chemistry
Quick revision notes for Chemical Kinetics — Tamil Nadu Board Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
1. Rate of Chemical Reaction - Fundamentals
- Rate is the change in concentration of reactants or products per unit time
- For reactants: Rate = -Δ[A]/Δt (negative sign because concentration decreases)
- For products: Rate = +Δ[B]/Δt (positive because concentration increases)
2. Rate Law and Rate Constant
- Rate law expresses how rate depends on concentrations of reactants
- Rate law CANNOT be predicted from balanced equation - must be determined experimentally
- Order of reaction = sum of powers of concentration terms in rate law
3. Molecularity and Reaction Mechanism
- Molecularity = total number of reactant molecules in a single elementary step
- Molecularity is always a whole number (1, 2, or 3) - never fractional
- Molecularity applies to elementary steps ONLY, not to overall reaction
4. Integrated Rate Equations
- Integrated rate equations contain time as variable - answer questions about concentration at specific times
- Different forms for zero, first, and higher-order reactions
- First-order reactions: ln[A] vs t is linear; slope = -k; intercept = ln[A]₀
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