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Biomolecules

Maharashtra Board · Class 12 · Chemistry

Flashcards for Biomolecules — Maharashtra Board Class 12 Chemistry. Quick Q&A cards covering key concepts, definitions, and formulas.

44 questions20 flashcards5 concepts

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Card 1Carbohydrates Introduction

Define carbohydrates and give their general molecular formula representation.

Answer

Carbohydrates are polyhydroxy aldehydes or ketones or compounds which give rise to such units on hydrolysis. They are also called saccharides (Greek word 'sakkharon' means sugar). General formula: Cx(

Card 2Carbohydrates Classification

How are carbohydrates classified based on their hydrolysis behavior?

Answer

Carbohydrates are classified into three groups: 1) Monosaccharides - do not hydrolyze further (glucose, fructose) 2) Oligosaccharides - yield 2-10 monosaccharide units on hydrolysis (sucrose, maltose,

Card 3Monosaccharides Nomenclature

What is the IUPAC nomenclature system for monosaccharides? Give examples.

Answer

General name: Glycose. Aldose = contains aldehydic carbonyl group (-CHO). Ketose = contains ketonic carbonyl group (C=O). Names modified by number of carbons: Glucose (C6H12O6) = aldohexose (6C aldose

Card 4Glucose Preparation

Write the chemical equation for preparation of glucose from sucrose.

Answer

C12H22O11 + H2O → C6H12O6 + C6H12O6 (Sucrose) + H⁺, Δ → (Glucose) + (Fructose) Method: Sucrose is hydrolyzed by warming with dilute HCl or H2SO4 for 2 hours. Glucose crystallizes out first when ethan

Card 5Glucose Structure

How many chiral carbons are present in glucose? What is the significance of this?

Answer

Glucose has 4 chiral carbons (C-2, C-3, C-4, C-5). Significance: With n chiral carbons, maximum 2ⁿ optical isomers are possible. For aldohexose: 2⁴ = 16 optical isomers possible. Glucose is one of the

Card 6Glucose Ring Structure

Explain the ring structure of glucose and the concept of anomers.

Answer

Glucose exists in cyclic form due to reaction between -CHO group and -OH group at C-5, forming hemiacetal. This creates two ring structures (α and β anomers) that differ in configuration of C-1 (anome

Card 7Glucose Properties

Why does glucose give positive Tollens test and Fehling test?

Answer

Glucose gives positive Tollens and Fehling tests because it has a hemiacetal group in its ring structure, which is a potential aldehyde group. The hemiacetal can open to form the free aldehyde group (

Card 8Disaccharides

Write the hydrolysis equation of sucrose and explain why it's called 'inversion of sucrose'.

Answer

C12H22O11 + H2O → C6H12O6 + C6H12O6 (Sucrose) + H⁺/invertase → (D-(+)glucose) + (D-(-)fructose) [α]D²⁰ = +66.5° → [α]D²⁰ = +52.7° + [α]D²⁰ = -92.4° Called 'inversion' because: Sucrose is dextrorotato

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What are the important topics in Biomolecules for Maharashtra Board Class 12 Chemistry?
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