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Carbonyl Compounds and Carboxylic Acids

Tamil Nadu Board · Class 12 · Chemistry

Flashcards for Carbonyl Compounds and Carboxylic Acids — Tamil Nadu Board Class 12 Chemistry. Quick Q&A cards covering key concepts, definitions, and formulas.

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Card 1Structure of Carbonyl Group

What is the structure and hybridization of the carbonyl carbon in aldehydes and ketones?

Answer

The carbonyl carbon (C=O) is sp² hybridized with a planar geometry. It forms three σ-bonds using three sp² hybrid orbitals and one π-bond using the unhybridised 2p orbital. The C=O bond is polar due t

Card 2Nomenclature of Aldehydes and Ketones

Write the IUPAC name for the compound: CH₃-CH=CH-CHO

Answer

IUPAC Name: but-2-enal (Common name: crotonaldehyde). Breaking down the name: 'but' (4 carbons) + '2-ene' (double bond at position 2) + 'al' (aldehyde functional group). When naming aldehydes, the car

Card 3Nomenclature of Aldehydes and Ketones

Give the IUPAC name for: (CH₃)₂C=CH-CO-CH₃

Answer

IUPAC Name: 4-methylpent-3-en-2-one. Breaking it down: The longest chain contains 5 carbons (pentane). The ketone is at position 2 (pentan-2-one). There's a double bond at position 3 (pent-3-en-2-one)

Card 4Nucleophilic Addition Reactions

What is the general mechanism of nucleophilic addition reaction to carbonyl compounds?

Answer

Nucleophilic addition occurs in three steps: (1) The nucleophile (Nu⁻) attacks the electrophilic carbonyl carbon, using its lone pair to form a C-Nu σ-bond. (2) The π-electrons move to oxygen, forming

Card 5Addition of HCN

Complete the reaction: CH₃CHO + HCN → ?

Answer

CH₃CHO + HCN → CH₃CH(OH)CN (acetaldehyde cyanohydrin). The cyanide ion (CN⁻) attacks the carbonyl carbon of acetaldehyde, forming a cyanohydrin. This is a nucleophilic addition reaction. The cyanohydr

Card 6Addition of Alcohols

What happens when acetaldehyde reacts with 2 equivalents of methanol in presence of HCl?

Answer

CH₃CHO + 2CH₃OH → CH₃CH(OCH₃)₂ + H₂O (1,1-dimethoxymethane/acetal). This is an acetal formation reaction. The first methanol adds via nucleophilic addition to form a hemiacetal (CH₃CH(OH)OCH₃), which

Card 7Addition of Ammonia Derivatives

What product forms when acetone reacts with hydroxylamine?

Answer

(CH₃)₂C=O + H₂NOH → (CH₃)₂C=NOH (acetone oxime) + H₂O. This is a nucleophilic addition-elimination reaction. Hydroxylamine (-NH₂OH) attacks the carbonyl carbon forming a tetrahedral intermediate. The

Card 8Oxidation of Aldehydes

Write the balanced equation for the oxidation of acetaldehyde using acidified potassium dichromate.

Answer

2CH₃CHO + 2K₂Cr₂O₇ + 8H₂SO₄ → 2CH₃COOH + 2Cr₂(SO₄)₃ + 2K₂SO₄ + 7H₂O. Aldehydes are easily oxidized to carboxylic acids. The orange dichromate ion (Cr₂O₇²⁻) is reduced to green Cr³⁺ ion. This is a char

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What are the important topics in Carbonyl Compounds and Carboxylic Acids for Tamil Nadu Board Class 12 Chemistry?
Key topics in Carbonyl Compounds and Carboxylic Acids include Overview of Carbonyl Compounds and Carboxylic Acids, Carbonyl Compounds and Carboxylic Acids Overview, Preparation Methods of Aldehydes and Ketones. These are the concepts Tamil Nadu Board Class 12 examiners draw on most — study them first, then practise related questions.
How to score full marks in Carbonyl Compounds and Carboxylic Acids — Tamil Nadu Board Class 12 Chemistry?
Understand the core concepts first, then work through the 44 practice questions available for this chapter. Revise formulas and definitions regularly, and use flashcards for quick recall before the exam.
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There are 40 flashcards for Carbonyl Compounds and Carboxylic Acids covering key definitions, formulas, and concepts. Use them daily for 10–15 minutes for best results.

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