Ionic Equilibrium
Telangana Open School (TOSS) · Class 12 · Chemistry
Quick revision notes for Ionic Equilibrium — Telangana Open School (TOSS) Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
1. Concepts of Acids and Bases
- Arrhenius concept: Acids produce H⁺ ions, bases produce OH⁻ ions in water.
- Bronsted-Lowry concept: Acids are proton donors, bases are proton acceptors.
- Lewis concept: Acids accept electron pairs, bases donate electron pairs.
2. Strength of Acids and Bases
- Strong acids/bases ionize completely in water; weak ones partially ionize.
- Ka (acid dissociation constant) measures strength of weak acids.
- Kb (base dissociation constant) measures strength of weak bases.
3. Self-Ionization of Water and pH Scale
- Water undergoes auto-ionization: H₂O + H₂O ⇌ H₃O⁺ + OH⁻.
- Ionic product of water, Kw = [H₃O⁺][OH⁻] = 1.0 × 10⁻¹⁴ at 298 K.
- pH = -log[H₃O⁺], pOH = -log[OH⁻], and pH + pOH = 14.
4. Common Ion Effect and Buffer Solutions
- Common ion effect suppresses ionization of weak acids or bases when a salt with the same ion is added.
- Buffer solutions resist pH change upon addition of small amounts of acid or base.
- Acidic buffers: weak acid + its salt (e.g., CH₃COOH + CH₃COONa).
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