Periodic Table and Atomic Properties — Revision Notes
Telangana Open School (TOSS) · Class 12 · Chemistry
Periodic Table and Atomic Properties revision notes for Telangana Open School (TOSS) Class 12 Chemistry: 4 topics in quick points.
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Key Topics to Revise
Historical Development of the Periodic Table
- J.W. Dobereiner proposed the Law of Triads: the atomic weight of the middle element in a triad is approximately the average of the other two.
- J.A.R. Newlands introduced the Law of Octaves, stating that every eighth element has similar properties, like musical notes.
- Mendeleev's Periodic Table arranged elements by increasing atomic weight and left gaps for undiscovered elements, predicting their properties.
Modern Periodic Law and Table Structure
- Modern Periodic Law: Properties of elements are periodic functions of their atomic numbers.
- The long form of the periodic table has 18 groups and 7 periods.
- Elements are classified into s-, p-, d-, and f-blocks based on the subshell in which the differentiating electron enters.
Electronic Configuration and Periodicity
- The period number corresponds to the principal quantum number (n) of the valence shell.
- Number of elements in a period depends on the number of orbitals being filled: 2 in period 1, 8 in periods 2–3, 18 in 4–5, 32 in 6–7.
- s-Block: ns¹⁻²; p-Block: ns² np¹⁻⁶; d-Block: (n−1)d¹⁻¹⁰ ns⁰⁻²; f-Block: (n−2)f¹⁻¹⁴ (n−1)d⁰⁻¹ ns².
Periodic Trends in Atomic Properties
- Atomic size decreases across a period (left to right) due to increasing nuclear charge pulling electrons closer.
- Atomic size increases down a group due to addition of new electron shells.
- Cations are smaller than their parent atoms; anions are larger.
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