Coordination Compounds
Telangana Open School (TOSS) · Class 12 · Chemistry
Quick revision notes for Coordination Compounds — Telangana Open School (TOSS) Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
Werner's Coordination Theory
- Metals exhibit two types of valency: primary (ionizable) and secondary (non-ionizable).
- Primary valency corresponds to the oxidation state and is satisfied by anions.
- Secondary valency is the coordination number and is satisfied by ligands (neutral or charged).
Important Terms in Coordination Chemistry
- Ligand: molecule or ion bonded to the central metal via lone pair donation.
- Monodentate ligands donate one electron pair (e.g., H₂O, NH₃).
- Bidentate ligands donate two electron pairs (e.g., ethylenediamine 'en').
Nomenclature of Coordination Compounds
- Cation named before anion.
- Ligands named first in alphabetical order (ignoring prefixes), then metal.
- Anionic ligands end in '-o' (e.g., Cl⁻ → chloro), neutral ligands use common name (e.g., NH₃ → ammine).
Valence Bond Theory (VBT)
- VBT explains geometry and magnetic behavior via hybridization.
- Inner orbital complexes use (n-1)d orbitals — low spin, diamagnetic or less paramagnetic.
- Outer orbital complexes use nd orbitals — high spin, more paramagnetic.
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