p-block Elements and their Compounds - I
Telangana Open School (TOSS) · Class 12 · Chemistry
Quick revision notes for p-block Elements and their Compounds - I — Telangana Open School (TOSS) Class 12 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
Boron and Its Compounds
- Boric acid (H₃BO₃) is prepared by reacting borax with sulfuric acid: Na₂B₄O₇ + H₂SO₄ + 5H₂O → Na₂SO₄ + 4H₃BO₃
- Boric acid is a weak Lewis acid, not a protonic acid. It accepts OH⁻ from water: B(OH)₃ + 2H₂O ⇌ [B(OH)₄]⁻ + H₃O⁺
- On heating, boric acid forms metaboric acid and then boric oxide (B₂O₃)
Aluminium and Double Salts
- Aluminium trichloride exists as dimer Al₂Cl₆ with two chlorine atoms forming dative bonds to complete octet
- Anhydrous AlCl₃ is a Lewis acid catalyst in Friedel-Crafts reactions
- Alums are double salts with general formula M⁺M³⁺(SO₄)₂·12H₂O where M⁺ = K⁺, NH₄⁺ and M³⁺ = Al³⁺, Cr³⁺, Fe³⁺
Carbon and Silicon Compounds
- Diamond has sp³ hybridized carbon atoms in a 3D tetrahedral network; graphite has sp² hybridized carbon in layers
- Graphite conducts electricity due to delocalized electrons; diamond does not
- CO is neutral and reducing; CO₂ is acidic and forms carbonates with bases
Nitrogen Compounds and Fertilizers
- Ammonia is prepared by Haber's process: N₂ + 3H₂ ⇌ 2NH₃ (Fe catalyst, 750K, 200 atm)
- Ammonia is a Lewis base due to lone pair on nitrogen; forms complexes like [Cu(NH₃)₄]²⁺
- Nitric acid is prepared by Ostwald process: NH₃ → NO → NO₂ → HNO₃
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