Chemical Thermodynamics
Telangana Open School (TOSS) · Class 12 · Chemistry
Complete topic list for Chemical Thermodynamics in Telangana Open School (TOSS) Class 12 Chemistry. Key concepts, sub-topics, and what to focus on for board exams.
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Topics in Chemical Thermodynamics
1. System, Surroundings, and Types of Systems
- A system is the part of the universe under study; the rest is called surroundings.
- Isolated system: No exchange of matter or energy with surroundings (e.g., thermos flask).
- Closed system: Exchanges energy but not matter (e.g., hot water in a closed steel flask).
2. Exothermic and Endothermic Reactions
- Exothermic reactions release heat to surroundings (ΔH < 0).
- Endothermic reactions absorb heat from surroundings (ΔH > 0).
- Examples: Combustion (exothermic), photosynthesis (endothermic).
3. First Law of Thermodynamics and Internal Energy
- Energy cannot be created or destroyed — it only changes form (conservation of energy).
- Mathematically: ΔU = q + w
- Internal energy (U) is the total energy of a system — a state function.
4. Enthalpy and Its Applications
- Enthalpy (H) = U + pV; a state function.
- ΔH = q_p — enthalpy change equals heat absorbed at constant pressure.
- ΔH = ΔU + pΔV (for constant pressure).
Key Concepts
Central concept: Chemical Thermodynamics
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