Nomenclature and General Principles
Telangana Open School (TOSS) · Class 12 · Chemistry
Complete topic list for Nomenclature and General Principles in Telangana Open School (TOSS) Class 12 Chemistry. Key concepts, sub-topics, and what to focus on for board exams.
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Topics in Nomenclature and General Principles
Classification of Hydrocarbons
- Organic compounds are classified based on carbon chain structure: open-chain (aliphatic) and closed-chain (cyclic).
- Aliphatic compounds can be saturated (alkanes) or unsaturated (alkenes, alkynes).
- Cyclic compounds are further divided into homocyclic (carbocyclic) and heterocyclic.
IUPAC Nomenclature of Organic Compounds
- IUPAC names consist of prefix + word root + suffix.
- Word root indicates number of carbon atoms (e.g., Meth-, Eth-, Prop-).
- Suffix indicates saturation: -ane (alkane), -ene (alkene), -yne (alkyne).
Types of Reactions and Bond Fission
- Organic reactions involve breaking and forming of covalent bonds.
- Two types of bond fission: homolytic (equal electron sharing, forms free radicals) and heterolytic (unequal sharing, forms ions).
- Heterolytic fission produces carbocations (positively charged carbon) and carbanions (negatively charged carbon).
Electronic Effects in Covalent Bonds
- Inductive effect: permanent polarization due to electronegativity difference; decreases with distance.
- Groups with –I effect withdraw electrons (e.g., –NO₂, –CN, –F); +I effect releases electrons (e.g., alkyl groups).
- Electromeric effect: temporary complete transfer of π-electrons during reaction; occurs in multiple bonds.
Key Concepts
Central concept: Organic Chemistry Fundamentals
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