Spontaneity of Chemical reactions
Telangana Open School (TOSS) · Class 12 · Chemistry
Complete topic list for Spontaneity of Chemical reactions in Telangana Open School (TOSS) Class 12 Chemistry. Key concepts, sub-topics, and what to focus on for board exams.
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Topics in Spontaneity of Chemical reactions
Spontaneous vs Non-Spontaneous Processes
- A spontaneous process occurs naturally without continuous external input.
- A non-spontaneous process requires continuous external energy to proceed.
- Spontaneity does not mean fast — some spontaneous reactions are very slow (e.g., rusting).
Entropy and Its Role in Spontaneity
- Entropy (S) is a measure of randomness or disorder in a system.
- Higher disorder means higher entropy.
- Gases have higher entropy than liquids, which have higher entropy than solids.
Gibbs Energy and Prediction of Spontaneity
- Gibbs energy (G) combines enthalpy and entropy: G = H – TS.
- Change in Gibbs energy: ΔG = ΔH – TΔS.
- For a process at constant temperature and pressure:
Entropy Changes and Applications
- Entropy increases with temperature due to increased molecular motion.
- Phase transitions involve significant entropy changes: ΔS_fus = ΔH_fus / T_m, ΔS_vap = ΔH_vap / T_b.
- Third Law of Thermodynamics: The entropy of a pure, perfectly crystalline substance is zero at absolute zero (0 K).
Key Concepts
Central concept: Spontaneity of Chemical Reactions
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