Kinetic Theory of Gases
NIOS · Class 12 · Physics
Quick revision notes for Kinetic Theory of Gases — NIOS Class 12 Physics. Key concepts, formulas, and definitions for last-minute revision.
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Thermal Energy: Heat Capacity and Specific Heat
- Heat and temperature are DIFFERENT concepts: heat is energy transferred due to temperature difference; temperature is a measure of average kinetic energy of molecules.
- Specific heat capacity (C) is the amount of heat required to raise the temperature of 1 kg of a substance by 1°C or 1 K.
- Formula: ΔQ = mCΔθ, where ΔQ = heat supplied (J), m = mass (kg), C = specific heat (J kg⁻¹ K⁻¹), Δθ = temperature rise (K or °C).
Thermal Expansion: Linear, Superficial, and Cubical
- When heat is supplied to a substance, it expands. Expansion can be in length (linear), area (superficial), or volume (cubical).
- All three coefficients are interconnected: β = 2α and γ = 3α
- Linear expansion: Δl = α l₀ Δθ, where α = coefficient of linear expansion (unit: K⁻¹ or °C⁻¹)
Assumptions and Pressure of an Ideal Gas (Kinetic Theory)
- Kinetic Theory connects MACROSCOPIC properties (P, V, T) with MICROSCOPIC properties (mass, speed of molecules).
- An IDEAL GAS is one whose molecules are point masses with no intermolecular forces between them.
- At room temperature and low pressure, real gases behave approximately like ideal gases.
Kinetic Interpretation of Temperature and Mean Kinetic Energy
- Combining PV = (1/3)NmĈ² with ideal gas law PV = nRT gives the kinetic interpretation of temperature.
- Mean kinetic energy per molecule = (1/2)mĈ² = (3/2)kT, where k = Boltzmann constant = 1.38 × 10⁻²³ J K⁻¹
- CRITICAL INSIGHT: Kinetic energy of a molecule depends ONLY on absolute temperature T, NOT on its mass. At the same temperature, all gas molecules (heavy or light) have the SAME average kinetic energy
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