Kinetic Theory of Gases
NIOS · Class 12 · Physics
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Explore the full setState the expression for pressure exerted by an ideal gas on the walls of its container. What does each symbol represent?
Answer
Formula: P = (1/3) × ρ × c̄² Where: • P = Pressure exerted by the gas (Pa) • ρ = Density of the gas (kg/m³) • c̄² = Mean square speed of molecules (m²/s²) Alternate form: PV = (1/3) × M × c̄² Where …
Calculate the pressure exerted by 10²² molecules of oxygen, each of mass 5 × 10⁻²⁶ kg, in a hollow cube of side 10 cm, where the average translational speed of a molecule is 500 m/s.
Answer
Given: • N = 10²², m = 5 × 10⁻²⁶ kg, l = 10 cm = 0.10 m, u = 500 m/s Step 1 – Change in momentum per collision: 2mu = 2 × 5×10⁻²⁶ × 500 = 5×10⁻²³ kg·m/s Step 2 – Time between successive impacts: t =…
What are the six main assumptions of the Kinetic Theory of Gases?
Answer
1. A gas has a very large number of identical rigid molecules moving randomly with all possible velocities. Intermolecular forces are negligible. 2. Collisions between molecules and with walls are pe…
Why is the mean square speed (c̄²) NOT the same as the square of the mean speed (c̄)²? Illustrate with an example.
Answer
These are two different mathematical quantities and are NOT equal in general. Example: Five molecules with speeds 1, 2, 3, 4, 5 units. Mean speed: c̄ = (1+2+3+4+5)/5 = 15/5 = 3 units (c̄)² = 9 Mean…
Calculate the RMS speed of hydrogen molecules at 300 K. (Given: m(H₂) = 3.347 × 10⁻²⁷ kg, k = 1.38 × 10⁻²³ J/K)
Answer
Given: • T = 300 K • m = 3.347 × 10⁻²⁷ kg • k = 1.38 × 10⁻²³ J/K Formula: c_rms = √(3kT/m) Step 1 – Numerator: 3kT = 3 × 1.38×10⁻²³ × 300 = 3 × 4.14×10⁻²¹ = 1.242×10⁻²⁰ J Step 2 – Divide by mass: 1…
At what temperature will the RMS speed of hydrogen molecules be double its value at STP (Standard Temperature = 273 K)?
Answer
Given: • Initial temperature T₀ = 273 K • Required: c_rms = 2 × c₀ (double the initial RMS speed) Key relation: c_rms ∝ √T Step 1 – Set up ratio: c/c₀ = √(T/T₀) 2c₀/c₀ = √(T/273) 2 = √(T/273) Step …
State the kinetic interpretation of temperature. What happens to molecular motion at absolute zero?
Answer
Kinetic Interpretation of Temperature: The mean kinetic energy of a gas molecule depends ONLY on the absolute temperature T and is independent of its mass. Formula: (1/2)mc̄² = (3/2)kT Where k = Bol…
Calculate the average kinetic energy of a gas molecule at 300 K. (Given: k = 1.38 × 10⁻²³ J/K)
Answer
Given: • T = 300 K • k = 1.38 × 10⁻²³ J/K Formula: Ē = (3/2)kT Step 1 – Substitute values: Ē = (3/2) × 1.38×10⁻²³ × 300 Step 2 – Calculate: Ē = 1.5 × 4.14×10⁻²¹ Ē = 6.21×10⁻²¹ J Answer: Ē = 6.21 ×…
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